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Solutions question

2022 · 29 Jul · Shift 1 · Q19
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Solutions question

2022 · 29 Jul · Shift 1 · Q19

JEE MainChemistrySolutionsNumerical+4 / −1
If O2\mathrm{O}_{2}O2​ gas is bubbled through water at 303 K303 \mathrm{~K}303 K, the number of millimoles of O2\mathrm{O}_{2}O2​ gas that dissolve in 1 litre of water is ‾\underline{\hspace{2cm}}​. (Nearest Integer) (Given : Henry's Law constant for O2\mathrm{O}_{2}O2​ at 303 K303 \mathrm{~K}303 K is 46.82 k46.82 \,\mathrm{k}46.82k bar and partial pressure of O2=0.920\mathrm{O}_{2}=0.920O2​=0.920 bar) (Assume solubility of O2\mathrm{O}_{2}O2​ in water is too small, nearly negligible)
Numerical answer
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Correct answer: 1

  1. Use Henry’s law

    For a gas dissolved in a liquid, p=KHxp = K_H xp=KH​x where:

    • ppp = partial pressure of the gas
    • KHK_HKH​ = Henry’s law constant
    • xxx = mole fraction of dissolved gas

    Given: KH=46.82 kbar=46.82×103 barK_H = 46.82\ \text{kbar} = 46.82 \times 10^3\ \text{bar}KH​=46.82 kbar=46.82×103 bar p=0.920 barp = 0.920\ \text{bar}p=0.920 bar

  2. Calculate mole fraction of dissolved O2\mathrm{O_2}O2​

    x=pKH=0.92046.82×103x = \frac{p}{K_H} = \frac{0.920}{46.82\times 10^3}x=KH​p​=46.82×1030.920​

    x≈1.965×10−5x \approx 1.965 \times 10^{-5}x≈1.965×10−5

  3. Relate mole fraction to moles dissolved

    Since solubility is very small, moles of dissolved O2\mathrm{O_2}O2​ are negligible compared to moles of water.

    For 111 litre of water: mass of water≈1000 g\text{mass of water} \approx 1000\ \text{g}mass of water≈1000 g nH2O=100018≈55.56 moln_{\mathrm{H_2O}} = \frac{1000}{18} \approx 55.56\ \text{mol}nH2​O​=181000​≈55.56 mol

    Now, x=nO2nO2+nH2O≈nO255.56x = \frac{n_{\mathrm{O_2}}}{n_{\mathrm{O_2}} + n_{\mathrm{H_2O}}} \approx \frac{n_{\mathrm{O_2}}}{55.56}x=nO2​​+nH2​O​nO2​​​≈55.56nO2​​​

    Therefore, nO2=x×55.56n_{\mathrm{O_2}} = x \times 55.56nO2​​=x×55.56

    nO2=1.965×10−5×55.56n_{\mathrm{O_2}} = 1.965 \times 10^{-5} \times 55.56nO2​​=1.965×10−5×55.56

    nO2≈1.092×10−3 moln_{\mathrm{O_2}} \approx 1.092 \times 10^{-3}\ \text{mol}nO2​​≈1.092×10−3 mol

  4. Convert to millimoles

    1.092×10−3 mol=1.092 mmol1.092 \times 10^{-3}\ \text{mol} = 1.092\ \text{mmol}1.092×10−3 mol=1.092 mmol

  5. Nearest integer

    1\boxed{1}1​

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