JEE MainChemistrySolutionsNumerical+4 / −1
Elevation in boiling point for 1.5 molal solution of glucose in water is 4 K. The depression in freezing point for 4.5 molal solution of glucose in water is 4 K. The ratio of molal elevation constant to molal depression constant (Kb/Kf) is .
Numerical answer
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Correct answer: 3
- Use colligative property formulas
For a non-electrolyte like glucose, van't Hoff factor .
So,
- From the boiling point data
Given:
- Molality
- Elevation in boiling point
Thus,
- From the freezing point data
Given:
- Molality
- Depression in freezing point
Thus,
- Find the ratio
Cancel :
- Final answer
The derived answer matches the stored correct answer.
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