JEE MainChemistrySolutionsNumerical+4 / −1
A gaseous mixture of two substances A and B, under a total pressure of atm is in equilibrium with an ideal liquid solution. The mole fraction of substance A is in the vapour phase and in the liquid phase. The vapour pressure of pure liquid is atm. (Nearest integer)
Numerical answer
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Correct answer: 2
- Given data
- Total pressure of vapour mixture:
- Mole fraction of in vapour phase:
- Mole fraction of in liquid phase:
- The liquid solution is ideal
We need to find vapour pressure of pure liquid , i.e. .
- Use Dalton’s law to find partial pressure of in vapour
For the vapour phase,
So,
- Use Raoult’s law for an ideal solution
For component ,
Substitute the values:
Therefore,
- Nearest integer
So the required integer answer is:
- Comparison with stored answer
Stored correct answer =
Our derived answer also =
Hence, the answer agrees with the stored correct answer.
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