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Redox Reactions question

2020 · 2 Sep · Shift 2 · Q4
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Redox Reactions question

2020 · 2 Sep · Shift 2 · Q4

JEE MainChemistryRedox ReactionsNumerical+4 / −1
The oxidation states of transition metal atoms in K2Cr2O7K_2Cr_2O_7K2​Cr2​O7​, KMnO4KMnO_4KMnO4​ and K2FeO4K_2FeO_4K2​FeO4​, respectively, are x, y and z. The sum of x, y and z is ‾\underline{\hspace{2cm}}​.
Numerical answer
View written solutionFree

Correct answer: 19

  1. Find oxidation state of Cr in K2Cr2O7K_2Cr_2O_7K2​Cr2​O7​

Let the oxidation state of Cr be xxx.

Using charge balance: 2(+1)+2x+7(−2)=02(+1) + 2x + 7(-2) = 02(+1)+2x+7(−2)=0 2+2x−14=02 + 2x - 14 = 02+2x−14=0 2x−12=02x - 12 = 02x−12=0 2x=122x = 122x=12 x=+6x = +6x=+6

  1. Find oxidation state of Mn in KMnO4KMnO_4KMnO4​

Let the oxidation state of Mn be yyy.

Using charge balance: +1+y+4(−2)=0+1 + y + 4(-2) = 0+1+y+4(−2)=0 1+y−8=01 + y - 8 = 01+y−8=0 y−7=0y - 7 = 0y−7=0 y=+7y = +7y=+7

  1. Find oxidation state of Fe in K2FeO4K_2FeO_4K2​FeO4​

Let the oxidation state of Fe be zzz.

Using charge balance: 2(+1)+z+4(−2)=02(+1) + z + 4(-2) = 02(+1)+z+4(−2)=0 2+z−8=02 + z - 8 = 02+z−8=0 z−6=0z - 6 = 0z−6=0 z=+6z = +6z=+6

  1. Sum of oxidation states

x+y+z=6+7+6=19x + y + z = 6 + 7 + 6 = 19x+y+z=6+7+6=19

Therefore, the required integer is: 19\boxed{19}19​

  1. Comparison with stored correct answer

Stored correct answer = 191919

Our derived answer also equals 191919, so the answers agree.

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