JEE MainChemistryPractical Organic ChemistryNumerical+4 / −1
In Dumas' method for estimation of nitrogen 1 g of an organic compound gave 150 mL of nitrogen collected at 300 K temperature and 900 mm Hg pressure. The percentage composition of nitrogen in the compound is % (nearest integer) (Aqueous tension at )
Numerical answer
View written solutionFree
Correct answer: 20
- Given data
- Mass of organic compound
- Volume of
- Temperature
- Total pressure
- Aqueous tension at
- Correct pressure of dry nitrogen
Since nitrogen is collected over water,
Convert into atm:
- Use ideal gas equation
So,
Substituting values:
Now calculate:
- Mass of nitrogen present
1 mole of has mass .
Therefore,
- Percentage of nitrogen
Nearest integer:
- Comparison with stored answer
Stored correct answer =
Our derived answer is also .
More from Practical Organic Chemistry
- A toxic compound " A " when reacted with NaCN in aqueous acidic medium yields an edible cooking component and food preservative " B ". " B " is converted to " C " by diborane and can be used as an additive to petrol to reduce emission. "C"…2025 · MCQ
- Match List - I with List - II Choose the correct answer from the options given below : Includes table2025 · MCQ
- In Dumas' method 292 mg of an organic compound released 50 mL of nitrogen gas at 300 K temperature and 715 mm Hg pressure. The percentage composition of ' N ' in the organic compound is…2025 · Numerical
- A mixture of 1 g each of chlorobenzene, aniline, and benzoic acid is dissolved in 50 mL ethyl acetate and placed in a separating funnel. 5 M NaOH (30 mL) was added in the same funnel. The funnel was shaken vigorously and then kept aside.…2025 · MCQ
- Given below are two statements: Statement I: In Lassaigne's test, the covalent organic molecules are transformed into ionic compounds. Statement II: The sodium fusion extract of an organic compound having N and S gives prussian blue colour…2025 · MCQ
- In Carius method of estimation of halogen, 0.25 g of an organic compound gave 0.15 g of silver bromide ( AgBr ). The percentage of Bromine in the organic compound is (Nearest integer). (Given :…2025 · Numerical
- In the sulphur estimation, 0.20 g of a pure organic compound gave 0.40 g of barium sulphate. The percentage of sulphur in the compound is . (Molar mass : …2025 · Numerical
- In Kjeldahl's method for estimation of nitrogen, acts as :2024 · MCQ