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Practical Organic Chemistry question

2025 · 4 Apr · Shift 1 · Q22
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Practical Organic Chemistry question

2025 · 4 Apr · Shift 1 · Q22

JEE MainChemistryPractical Organic ChemistryNumerical+4 / −1
In Dumas' method for estimation of nitrogen 1 g of an organic compound gave 150 mL of nitrogen collected at 300 K temperature and 900 mm Hg pressure. The percentage composition of nitrogen in the compound is ‾\underline{\hspace{2cm}}​ % (nearest integer) (Aqueous tension at 300 K=15 mm Hg300 \mathrm{~K}=15 \mathrm{~mm} \mathrm{~Hg}300 K=15 mm Hg )
Numerical answer
View written solutionFree

Correct answer: 20

  1. Given data
  • Mass of organic compound =1.0 g= 1.0\,\text{g}=1.0g
  • Volume of N2=150 mL=0.150 LN_2 = 150\,\text{mL} = 0.150\,\text{L}N2​=150mL=0.150L
  • Temperature =300 K= 300\,\text{K}=300K
  • Total pressure =900 mm Hg= 900\,\text{mm Hg}=900mm Hg
  • Aqueous tension at 300 K=15 mm Hg300\,\text{K} = 15\,\text{mm Hg}300K=15mm Hg
  1. Correct pressure of dry nitrogen

Since nitrogen is collected over water, PN2=900−15=885 mm HgP_{N_2} = 900 - 15 = 885\,\text{mm Hg}PN2​​=900−15=885mm Hg

Convert into atm: PN2=885760 atmP_{N_2} = \frac{885}{760}\,\text{atm}PN2​​=760885​atm

  1. Use ideal gas equation

PV=nRTPV = nRTPV=nRT

So, n=PVRTn = \frac{PV}{RT}n=RTPV​

Substituting values: n=(885760)(0.150)(0.0821)(300)n = \frac{\left(\frac{885}{760}\right)(0.150)}{(0.0821)(300)}n=(0.0821)(300)(760885​)(0.150)​

Now calculate: 885760≈1.1645\frac{885}{760} \approx 1.1645760885​≈1.1645

n≈1.1645×0.15024.63n \approx \frac{1.1645 \times 0.150}{24.63}n≈24.631.1645×0.150​

n≈0.174724.63≈0.00709 mol of N2n \approx \frac{0.1747}{24.63} \approx 0.00709\,\text{mol of } N_2n≈24.630.1747​≈0.00709mol of N2​

  1. Mass of nitrogen present

1 mole of N2N_2N2​ has mass 28 g28\,\text{g}28g.

Therefore, mass of nitrogen=0.00709×28\text{mass of nitrogen} = 0.00709 \times 28mass of nitrogen=0.00709×28

≈0.1985 g\approx 0.1985\,\text{g}≈0.1985g

  1. Percentage of nitrogen

%N=0.19851.0×100\%N = \frac{0.1985}{1.0} \times 100%N=1.00.1985​×100

%N≈19.85%\%N \approx 19.85\%%N≈19.85%

Nearest integer: 20\boxed{20}20​

  1. Comparison with stored answer

Stored correct answer = 202020

Our derived answer is also 202020.

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