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Practical Organic Chemistry question

2025 · 7 Apr · Shift 2 · Q21
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Practical Organic Chemistry question

2025 · 7 Apr · Shift 2 · Q21

JEE MainChemistryPractical Organic ChemistryNumerical+4 / −1
In Dumas' method 292 mg of an organic compound released 50 mL of nitrogen gas (N2)\left(\mathrm{N}_2\right)(N2​) at 300 K temperature and 715 mm Hg pressure. The percentage composition of ' N ' in the organic compound is ‾\underline{\hspace{2cm}}​ % (Nearest integer) (Aqueous tension at 300 K=15 mmHg300 \mathrm{~K}=15 \mathrm{~mm} \mathrm{Hg}300 K=15 mmHg )
Numerical answer
View written solutionFree

Correct answer: 18

  1. Given data
  • Mass of organic compound =292 mg=0.292 g= 292\,\text{mg} = 0.292\,\text{g}=292mg=0.292g
  • Volume of N2\mathrm{N_2}N2​ gas =50 mL=0.050 L= 50\,\text{mL} = 0.050\,\text{L}=50mL=0.050L
  • Temperature =300 K= 300\,\text{K}=300K
  • Total pressure =715 mm Hg= 715\,\text{mm Hg}=715mm Hg
  • Aqueous tension at 300 K=15 mm Hg300\,\text{K} = 15\,\text{mm Hg}300K=15mm Hg

So, pressure of dry nitrogen gas is PN2=715−15=700 mm HgP_{\mathrm{N_2}} = 715 - 15 = 700\,\text{mm Hg}PN2​​=715−15=700mm Hg

Convert into atm: P=700760 atmP = \frac{700}{760}\,\text{atm}P=760700​atm

  1. Use ideal gas equation to find moles of nitrogen gas

n=PVRTn = \frac{PV}{RT}n=RTPV​

Substituting, n=(700760)(0.050)(0.0821)(300)n = \frac{\left(\frac{700}{760}\right)(0.050)}{(0.0821)(300)}n=(0.0821)(300)(760700​)(0.050)​

n≈0.0460524.63≈1.87×10−3 mol of N2n \approx \frac{0.04605}{24.63} \approx 1.87 \times 10^{-3}\,\text{mol of } \mathrm{N_2}n≈24.630.04605​≈1.87×10−3mol of N2​

  1. Mass of nitrogen present

Each mole of N2\mathrm{N_2}N2​ has mass 28 g28\,\text{g}28g.

mN=n×28m_{\mathrm{N}} = n \times 28mN​=n×28

mN=1.87×10−3×28m_{\mathrm{N}} = 1.87 \times 10^{-3} \times 28mN​=1.87×10−3×28

mN≈0.0524 g=52.4 mgm_{\mathrm{N}} \approx 0.0524\,\text{g} = 52.4\,\text{mg}mN​≈0.0524g=52.4mg

  1. Percentage of nitrogen in compound

%N=mass of nitrogenmass of compound×100\%N = \frac{\text{mass of nitrogen}}{\text{mass of compound}} \times 100%N=mass of compoundmass of nitrogen​×100

%N=0.05240.292×100\%N = \frac{0.0524}{0.292} \times 100%N=0.2920.0524​×100

%N≈17.95%\%N \approx 17.95\%%N≈17.95%

Nearest integer: 18\boxed{18}18​

  1. Comparison with stored answer

Stored correct answer = 181818

Our derived answer also is 181818, so it agrees.

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