- AMethanol; acetic acid; ethanol; diethyl ether
- BEthanol; acetonitrile; ethylamine; ethylene
- CMethanol; formaldehyde; methyl chloride; chloroform
- DAcetaldehyde; 2-hydroxypropanoic acid; propanoic acid; dipropyl ether
View written solutionFree
Correct answer: A
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We identify compound first.
The question says a toxic compound reacts with in aqueous acidic medium to give an edible cooking component and food preservative .
A very common edible cooking component and preservative is acetic acid (vinegar).
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Check how acetic acid can be formed from a toxic compound using .
Methanol can first be converted to a cyanide derivative and then hydrolyzed to acetic acid overall. In practical organic chemistry, this corresponds to chain extension via cyanide followed by hydrolysis.
So:
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Now convert to using diborane.
Diborane can reduce carboxylic acids to primary alcohols:
Hence,
Ethanol is indeed used as a petrol additive (blended fuel) to reduce emissions.
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Now convert to using oleum at .
Ethanol on dehydration at about in acidic medium gives diethyl ether:
Diethyl ether is a well-known inhalation anesthetic.
Therefore,
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Match with options.
The sequence is:
This matches Option A.
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Verification of other options:
- B: acetonitrile is not an edible cooking component/preservative.
- C: formaldehyde is not edible and chloroform is not obtained this way.
- D: 2-hydroxypropanoic acid is lactic acid, not the stated food preservative in this context.
Therefore, the correct answer is Option A.
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