Sign in
12thPass logo
New chatPYQ LibraryDoubtsRank report
Sign in to see Recents

Your guest activity stays on this device

Sign in to save progress →
Sign in

Practical Organic Chemistry question

2025 · 4 Apr · Shift 2 · Q11
Guest · filters and generic practice availableBrowsing as a guest · PYQ filters and generic practice are available. Sign in only for personalised features and saved progress.
  1. PYQ Library
  2. /JEE Main
  3. /Chemistry
  4. /Practical Organic Chemistry
  5. /2025 · 4 Apr · Shift 2 · Q11

Practical Organic Chemistry question

2025 · 4 Apr · Shift 2 · Q11

JEE MainChemistryPractical Organic ChemistryMCQ+4 / −1
A toxic compound " A " when reacted with NaCN in aqueous acidic medium yields an edible cooking component and food preservative " B ". " B " is converted to " C " by diborane and can be used as an additive to petrol to reduce emission. "C" upon reaction with oleum at 140∘C140^{\circ} \mathrm{C}140∘C yields an inhalable anesthetic " D ". Identify " A ", " B ", " C " & " D ", respectively :
  1. A
    Methanol; acetic acid; ethanol; diethyl ether
  2. B
    Ethanol; acetonitrile; ethylamine; ethylene
  3. C
    Methanol; formaldehyde; methyl chloride; chloroform
  4. D
    Acetaldehyde; 2-hydroxypropanoic acid; propanoic acid; dipropyl ether
View written solutionFree

Correct answer: A

  1. We identify compound AAA first.

    The question says a toxic compound AAA reacts with NaCN\text{NaCN}NaCN in aqueous acidic medium to give an edible cooking component and food preservative BBB.

    A very common edible cooking component and preservative is acetic acid (vinegar).

  2. Check how acetic acid can be formed from a toxic compound using NaCN/H+\text{NaCN}/\text{H}^+NaCN/H+.

    Methanol can first be converted to a cyanide derivative and then hydrolyzed to acetic acid overall. In practical organic chemistry, this corresponds to chain extension via cyanide followed by hydrolysis.

    So: A=methanol,B=acetic acidA = \text{methanol}, \qquad B = \text{acetic acid}A=methanol,B=acetic acid

  3. Now convert BBB to CCC using diborane.

    Diborane can reduce carboxylic acids to primary alcohols: CH3COOH→B2H6CH3CH2OH\text{CH}_3\text{COOH} \xrightarrow{B_2H_6} \text{CH}_3\text{CH}_2\text{OH}CH3​COOHB2​H6​​CH3​CH2​OH

    Hence, C=ethanolC = \text{ethanol}C=ethanol

    Ethanol is indeed used as a petrol additive (blended fuel) to reduce emissions.

  4. Now convert CCC to DDD using oleum at 140∘C140^\circ C140∘C.

    Ethanol on dehydration at about 140∘C140^\circ C140∘C in acidic medium gives diethyl ether: 2 C2H5OH→140∘Cconc. acid / oleumC2H5−O−C2H5+H2O2\,\text{C}_2\text{H}_5\text{OH} \xrightarrow[140^\circ C]{\text{conc. acid / oleum}} \text{C}_2\text{H}_5-O-\text{C}_2\text{H}_5 + H_2O2C2​H5​OHconc. acid / oleum140∘C​C2​H5​−O−C2​H5​+H2​O

    Diethyl ether is a well-known inhalation anesthetic.

    Therefore, D=diethyl etherD = \text{diethyl ether}D=diethyl ether

  5. Match with options.

    The sequence is: A=Methanol,B=acetic acid,C=ethanol,D=diethyl etherA = \text{Methanol}, \quad B = \text{acetic acid}, \quad C = \text{ethanol}, \quad D = \text{diethyl ether}A=Methanol,B=acetic acid,C=ethanol,D=diethyl ether

    This matches Option A.

  6. Verification of other options:

    • B: acetonitrile is not an edible cooking component/preservative.
    • C: formaldehyde is not edible and chloroform is not obtained this way.
    • D: 2-hydroxypropanoic acid is lactic acid, not the stated food preservative in this context.

Therefore, the correct answer is Option A.

PreviousNext

More from Practical Organic Chemistry

  • Match List - I with List - II Choose the correct answer from the options given below : Includes table2025 · MCQ
  • In Dumas' method 292 mg of an organic compound released 50 mL of nitrogen gas (N2​) at 300 K temperature and 715 mm Hg pressure. The percentage composition of ' N ' in the organic compound is…2025 · Numerical
  • A mixture of 1 g each of chlorobenzene, aniline, and benzoic acid is dissolved in 50 mL ethyl acetate and placed in a separating funnel. 5 M NaOH (30 mL) was added in the same funnel. The funnel was shaken vigorously and then kept aside.…2025 · MCQ
  • Given below are two statements: Statement I: In Lassaigne's test, the covalent organic molecules are transformed into ionic compounds. Statement II: The sodium fusion extract of an organic compound having N and S gives prussian blue colour…2025 · MCQ
  • In Carius method of estimation of halogen, 0.25 g of an organic compound gave 0.15 g of silver bromide ( AgBr ). The percentage of Bromine in the organic compound is ​×10−1%(Nearest integer). (Given :…2025 · Numerical
  • In the sulphur estimation, 0.20 g of a pure organic compound gave 0.40 g of barium sulphate. The percentage of sulphur in the compound is ​×10−1%. (Molar mass : O=16, S=32,Ba=137…2025 · Numerical
  • In Kjeldahl's method for estimation of nitrogen, CuSO4​ acts as :2024 · MCQ
  • Given below are two statements : Statement (I) : Potassium hydrogen phthalate is a primary standard for standardisation of sodium hydroxide solution. Statement (II) : In this titration phenolphthalein can be used as indicator. In the light…2024 · MCQ