JEE MainChemistryPractical Organic ChemistryMCQ+4 / −1
An organic compound 'X' showing the following solubility profile is : 

- Ao-Toluidine
- BBenzamide
- COleic acid
- Dm-Cresol
View written solutionFree
Correct answer: D
-
In practical organic analysis, solubility behavior is used to identify the functional group.
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The usual diagnostic pattern for the given options is:
- Carboxylic acids dissolve in as well as .
- Phenols dissolve in but not in .
- Amines dissolve in dilute .
- Amides are generally neutral and do not show such acidic/basic solubility.
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Now check each option:
A: -Toluidine
- It is an amine.
- It should dissolve in dilute due to salt formation.
- So this does not match a phenolic solubility profile.
B: Benzamide
- It is an amide.
- It is neutral and does not characteristically dissolve in like a phenol.
- So this is not the correct match.
C: Oleic acid
- It is a carboxylic acid.
- It should dissolve in and .
- Hence it would not fit a profile of dissolving only in strong base.
D: -Cresol
- It is a phenol.
- Phenols dissolve in but not in .
- This matches the characteristic practical organic solubility profile.
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Therefore, compound is -Cresol.
- Comparison with stored correct answer:
- Stored correct answer: D
- Derived answer: D
- They match.
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