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Practical Organic Chemistry question

2018 · Shift 0 · Q10
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Practical Organic Chemistry question

2018 · Shift 0 · Q10

JEE MainChemistryPractical Organic ChemistryMCQ+4 / −1
Which of the following compounds will be suitable for Kjeldahl’s method for nitrogen estimation?
  1. A
    JEE Main 2018 (Offline) Chemistry - Practical Organic Chemistry Question 87 English Option 1
  2. B
    JEE Main 2018 (Offline) Chemistry - Practical Organic Chemistry Question 87 English Option 2
  3. C
    JEE Main 2018 (Offline) Chemistry - Practical Organic Chemistry Question 87 English Option 3
  4. D
    JEE Main 2018 (Offline) Chemistry - Practical Organic Chemistry Question 87 English Option 4
View written solutionFree

Correct answer: C

  1. Principle of Kjeldahl’s method

    Kjeldahl’s method is used to estimate nitrogen when the nitrogen present in the compound can be converted into NH4+\mathrm{NH_4^+}NH4+​ (ammonium sulfate during digestion with conc. H2SO4\mathrm{H_2SO_4}H2​SO4​).

  2. Compounds for which Kjeldahl’s method is suitable

    It works well for:

    • amines
    • amides
    • aniline-like compounds
    • most ordinary nitrogen-containing organic compounds

    It is not suitable for compounds in which nitrogen is present as:

    • nitro group: −NO2-\mathrm{NO_2}−NO2​
    • azo group: −N=N−-\mathrm{N=N}-−N=N−
    • ring nitrogen in some heterocycles
    • diazo groups, etc.
  3. How to identify the correct option

    Since the options are not visible in the question text, the only chemistry criterion we can use is:

    • the suitable compound must contain nitrogen in a form that is converted to ammonium sulfate on digestion,
    • and must not contain nitro, azo, or similar resistant nitrogen forms.
  4. Comparison with stored answer

    The stored correct answer is C. This implies that option C is the compound having nitrogen in a Kjeldahl-suitable form (such as an amine or amide), while the other options likely contain nitrogen in unsuitable forms such as nitro/azo/ring nitrogen.

  5. Final answer

    Therefore, the suitable compound for Kjeldahl’s method is: C\boxed{\text{C}}C​

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