JEE MainChemistryPractical Organic ChemistryMCQ+4 / −1
For standardizing NaOH solution, which of the following is used as a primary standard ?
- AFerrous Ammonium Sulfate
- Bdil. HCl
- COxalic acid
- DSodium tetraborate
View written solutionFree
Correct answer: C
-
What is needed to standardize NaOH?
A primary standard must be:
- very pure,
- stable in air,
- non-hygroscopic,
- of known formula,
- easy to weigh accurately.
Since NaOH is a base, we standardize it using a suitable primary standard acid.
-
Check each option
A. Ferrous ammonium sulfate
- This is used in redox titrations, not for standardizing NaOH.
- So, not suitable.
B. dil. HCl
- Dilute HCl is not a primary standard because HCl is volatile and its concentration cannot be determined just by weighing accurately.
- So, not suitable.
C. Oxalic acid
- Oxalic acid (commonly as hydrated oxalic acid) is a well-known primary standard acid.
- It is commonly used to standardize NaOH solution.
- So, suitable.
D. Sodium tetraborate
- Sodium tetraborate (borax) is a primary standard base, generally used for standardizing acids, not NaOH.
- Since NaOH is also a base, this is not used for standardizing NaOH.
-
Conclusion
The correct primary standard used for standardizing NaOH is:
-
Comparison with stored correct answer
Stored correct answer: C
Derived answer: C
Hence, the derived answer agrees with the stored correct answer.
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