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Practical Organic Chemistry question

2018 · 16 Apr · Shift 1 · Q16
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Practical Organic Chemistry question

2018 · 16 Apr · Shift 1 · Q16

JEE MainChemistryPractical Organic ChemistryMCQ+4 / −1
For standardizing NaOH solution, which of the following is used as a primary standard ?
  1. A
    Ferrous Ammonium Sulfate
  2. B
    dil. HCl
  3. C
    Oxalic acid
  4. D
    Sodium tetraborate
View written solutionFree

Correct answer: C

  1. What is needed to standardize NaOH?

    A primary standard must be:

    • very pure,
    • stable in air,
    • non-hygroscopic,
    • of known formula,
    • easy to weigh accurately.

    Since NaOH is a base, we standardize it using a suitable primary standard acid.

  2. Check each option

    A. Ferrous ammonium sulfate

    • This is used in redox titrations, not for standardizing NaOH.
    • So, not suitable.

    B. dil. HCl

    • Dilute HCl is not a primary standard because HCl is volatile and its concentration cannot be determined just by weighing accurately.
    • So, not suitable.

    C. Oxalic acid

    • Oxalic acid (commonly as hydrated oxalic acid) is a well-known primary standard acid.
    • It is commonly used to standardize NaOH solution.
    • So, suitable.

    D. Sodium tetraborate

    • Sodium tetraborate (borax) is a primary standard base, generally used for standardizing acids, not NaOH.
    • Since NaOH is also a base, this is not used for standardizing NaOH.
  3. Conclusion

    The correct primary standard used for standardizing NaOH is: Oxalic acid\boxed{\text{Oxalic acid}}Oxalic acid​

  4. Comparison with stored correct answer

    Stored correct answer: C

    Derived answer: C

    Hence, the derived answer agrees with the stored correct answer.

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