| Test | Inference | |
|---|---|---|
| (a) | 2, 4 - DNP test | Coloured precipitate |
| (b) | Idoform test | Yellow precipitate |
| (c) | Azo-dye test | No dye formation |
Compound 'X' is :
- A

- B

- C

- D

View written solutionFree
Correct answer: B
-
Interpret each test result
We are given:
- 2,4-DNP test: coloured precipitate
- Iodoform test: yellow precipitate
- Azo-dye test: no dye formation
-
Inference from 2,4-DNP test
The -dinitrophenylhydrazine test is given by aldehydes and ketones.
So, compound must contain a carbonyl group of an aldehyde or ketone.
-
Inference from iodoform test
A positive iodoform test is given by compounds containing either:
- the methyl ketone group, , or
- alcohols of type , which get oxidized to methyl ketones.
But from step 2, since already gives 2,4-DNP, it must itself be a carbonyl compound, not just an alcohol.
Therefore, should be a methyl ketone:
-
Inference from azo-dye test
The azo-dye test is given by phenols (and certain aromatic amines after diazotization/coupling).
Since there is no dye formation, is not a phenol.
-
Combine all observations
So must be:
- a ketone,
- specifically a methyl ketone,
- and not a phenol.
Hence the correct option must be the one corresponding to a simple methyl ketone such as acetone / methyl ketone, which is given as Option B.
-
Conclusion
Therefore, compound is Option B.
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