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Periodic Table and Periodicity question

2020 · 9 Jan · Shift 1 · Q22
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Periodic Table and Periodicity question

2020 · 9 Jan · Shift 1 · Q22

JEE MainChemistryPeriodic Table and PeriodicityMCQ+4 / −1
B has a smaller first ionization enthalpy than Be. Consider the following statements : (I) It is easier to remove 2p electron than 2s electron (II) 2p electron of B is more shielded from the nucleus by the inner core of electrons than the 2s electrons of Be. (III) 2s electron has more penetration power than 2p electron. (IV) atomic radius of B is more than Be (Atomic number B = 5, Be = 4) The correct statements are :
  1. A
    (I), (III) and (IV)
  2. B
    (II), (III) and (IV)
  3. C
    (I), (II) and (IV)
  4. D
    (I), (II) and (III)
View written solutionFree

Correct answer: D

  1. Electronic configurations
  • Be (Z=4)(Z=4)(Z=4): 1s22s21s^2 2s^21s22s2
  • B (Z=5)(Z=5)(Z=5): 1s22s22p11s^2 2s^2 2p^11s22s22p1

The first ionization enthalpy of B is smaller than that of Be because the electron removed from B is a 2p2p2p electron, while from Be it is a 2s2s2s electron.


  1. Examine Statement (I):

It is easier to remove 2p2p2p electron than 2s2s2s electron.

This is true.

Reason: A 2p2p2p electron is higher in energy and less penetrating than a 2s2s2s electron, so it is held less strongly by the nucleus.


  1. Examine Statement (II):

2p2p2p electron of B is more shielded from the nucleus by the inner core of electrons than the 2s2s2s electrons of Be.

This is true in the intended periodic-trend sense.

Reason: The 2p2p2p electron is less penetrating and spends less time close to the nucleus than a 2s2s2s electron. Hence it experiences greater shielding and lower effective nuclear charge than a 2s2s2s electron of comparable shell.


  1. Examine Statement (III):

2s2s2s electron has more penetration power than 2p2p2p electron.

This is true.

Known order of penetration: s>p>d>fs > p > d > fs>p>d>f So 2s2s2s penetrates closer to the nucleus than 2p2p2p.


  1. Examine Statement (IV):

Atomic radius of B is more than Be.

This is false.

Across a period, atomic radius generally decreases from left to right due to increasing effective nuclear charge. Thus, r(B)<r(Be)r(\text{B}) < r(\text{Be})r(B)<r(Be) So this statement is incorrect.


  1. Correct combination

True statements are:

  • (I) True
  • (II) True
  • (III) True
  • (IV) False

Therefore, the correct option is: D: (I), (II) and (III)\boxed{\text{D: (I), (II) and (III)}}D: (I), (II) and (III)​

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