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Periodic Table and Periodicity question

2020 · 8 Jan · Shift 2 · Q2
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Periodic Table and Periodicity question

2020 · 8 Jan · Shift 2 · Q2

JEE MainChemistryPeriodic Table and PeriodicityMCQ+4 / −1
The increasing order of the atomic radii of the following elements is :- (a) C (b) O (c) F (d) Cl (e) Br
  1. A
    (a) < (b) < (c) < (d) < (e)
  2. B
    (c) < (b) < (a) < (d) < (e)
  3. C
    (b) < (c) < (d) < (a) < (e)
  4. D
    (d) < (c) < (b) < (a) < (e)
View written solutionFree

Correct answer: B

  1. Identify periodic trends

    Atomic radius:

    • decreases across a period from left to right due to increasing effective nuclear charge.
    • increases down a group because new shells are added.
  2. Compare the elements in Period 2

    The elements are:

    • C\text{C}C, O\text{O}O, F\text{F}F

    In Period 2, moving left to right: C>O>F\text{C} > \text{O} > \text{F}C>O>F So, increasing order among these three is: F<O<C\text{F} < \text{O} < \text{C}F<O<C

  3. Compare the halogens down the group

    The elements are:

    • F\text{F}F, Cl\text{Cl}Cl, Br\text{Br}Br

    Down Group 17, atomic radius increases: F<Cl<Br\text{F} < \text{Cl} < \text{Br}F<Cl<Br

  4. Combine all comparisons

    Since C\text{C}C is in Period 2 and lies to the left of F\text{F}F and O\text{O}O, it is larger than both F\text{F}F and O\text{O}O. Also, atoms in lower periods are generally larger, so: C<Cl<Br\text{C} < \text{Cl} < \text{Br}C<Cl<Br

    Therefore, the overall increasing order is: F<O<C<Cl<Br\boxed{\text{F} < \text{O} < \text{C} < \text{Cl} < \text{Br}}F<O<C<Cl<Br​

  5. Match with options

    Given labels:

    • (a)=C(a)=\text{C}(a)=C
    • (b)=O(b)=\text{O}(b)=O
    • (c)=F(c)=\text{F}(c)=F
    • (d)=Cl(d)=\text{Cl}(d)=Cl
    • (e)=Br(e)=\text{Br}(e)=Br

    So the order becomes: (c)<(b)<(a)<(d)<(e)(c) < (b) < (a) < (d) < (e)(c)<(b)<(a)<(d)<(e)

    This corresponds to Option B.

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