JEE MainChemistryP Block ElementsNumerical+4 / −1
A group 15 element forms bond with transition metals. It also forms hydride, which is a strongest base among the hydrides of other group members that form bond. The atomic number of the element is .
Numerical answer
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Correct answer: 15
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We need a group 15 element that:
- can form bonds with transition metals, and
- forms a hydride which is the strongest base among hydrides of the other group 15 members that also form bonds.
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Group 15 elements are:
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For forming bonds with transition metals, the element should have available orbitals.
- Nitrogen does not have vacant orbitals in its valence shell, so it is excluded.
- The elements that can participate are:
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Their hydrides are:
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In group 15, the basic strength of hydrides decreases down the group because the lone pair becomes less available for donation due to increasing size and poorer overlap effects. Hence:
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Therefore, among the group 15 elements capable of forming bonds, the element whose hydride is the strongest base is phosphorus.
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Atomic number of phosphorus is:
Therefore, the required atomic number is:
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