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P Block Elements question

2025 · 28 Jan · Shift 2 · Q25
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P Block Elements question

2025 · 28 Jan · Shift 2 · Q25

JEE MainChemistryP Block ElementsNumerical+4 / −1
A group 15 element forms dπ−dπ\mathrm{d} \pi-\mathrm{d} \pidπ−dπ bond with transition metals. It also forms hydride, which is a strongest base among the hydrides of other group members that form dπ−dπd \pi-d \pidπ−dπ bond. The atomic number of the element is ‾\underline{\hspace{2cm}}​ .
Numerical answer
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Correct answer: 15

  1. We need a group 15 element that:

    • can form dπ−dπd\pi-d\pidπ−dπ bonds with transition metals, and
    • forms a hydride which is the strongest base among hydrides of the other group 15 members that also form dπ−dπd\pi-d\pidπ−dπ bonds.
  2. Group 15 elements are: N, P, As, Sb, Bi\mathrm{N,\, P,\, As,\, Sb,\, Bi}N,P,As,Sb,Bi

  3. For forming dπ−dπd\pi-d\pidπ−dπ bonds with transition metals, the element should have available ddd orbitals.

    • Nitrogen does not have vacant ddd orbitals in its valence shell, so it is excluded.
    • The elements that can participate are: P, As, Sb, Bi\mathrm{P,\, As,\, Sb,\, Bi}P,As,Sb,Bi
  4. Their hydrides are: PH3, AsH3, SbH3, BiH3\mathrm{PH_3,\, AsH_3,\, SbH_3,\, BiH_3}PH3​,AsH3​,SbH3​,BiH3​

  5. In group 15, the basic strength of hydrides decreases down the group because the lone pair becomes less available for donation due to increasing size and poorer overlap effects. Hence: PH3>AsH3>SbH3>BiH3\mathrm{PH_3 > AsH_3 > SbH_3 > BiH_3}PH3​>AsH3​>SbH3​>BiH3​

  6. Therefore, among the group 15 elements capable of forming dπ−dπd\pi-d\pidπ−dπ bonds, the element whose hydride is the strongest base is phosphorus.

  7. Atomic number of phosphorus is: Z=15Z = 15Z=15

Therefore, the required atomic number is: 15\boxed{15}15​

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