JEE MainChemistryP Block ElementsMCQ+4 / −1
Identify the incorrect statements about group 15 elements : (A) Dinitrogen is a diatomic gas which acts like an inert gas at room temperature. (B) The common oxidation states of these elements are and +5. (C) Nitrogen has unique ability to form multiple bonds. (D) The stability of +5 oxidation states increases down the group. (E) Nitrogen shows a maximum covalency of 6. Choose the correct answer from the options given below :
- A(A), (C), (E) only
- B(D) and (E) only
- C(A), (B), (D) only
- D(B), (D), (E) only
View written solutionFree
Correct answer: B
- Check each statement for group 15 elements
Group 15 elements are: .
Their common properties include oxidation states and , and down the group the inert pair effect becomes more significant.
- Statement (A): Dinitrogen is a diatomic gas which acts like an inert gas at room temperature.
- is indeed a diatomic gas.
- It is very unreactive at room temperature because of the strong triple bond, .
- So it behaves almost inert at room temperature.
Hence, (A) is correct.
- Statement (B): The common oxidation states of these elements are and .
- This is a standard property of group 15 elements.
- Nitrogen commonly shows .
- Heavier members also commonly show and .
Hence, (B) is correct.
- Statement (C): Nitrogen has unique ability to form multiple bonds.
- Nitrogen, due to small size and high electronegativity, forms strong multiple bonds like:
- This is indeed a characteristic feature of nitrogen.
Hence, (C) is correct.
- Statement (D): The stability of oxidation states increases down the group.
- Due to inert pair effect, the stability of the lower oxidation state increases down the group.
- Therefore, the stability of the higher oxidation state decreases down the group.
So (D) is incorrect.
- Statement (E): Nitrogen shows a maximum covalency of 6.
- Nitrogen is a second-period element.
- It has no vacant -orbitals and cannot expand its octet.
- Therefore, its maximum covalency is 4, not 6.
So (E) is incorrect.
- Incorrect statements
The incorrect statements are:
This corresponds to Option B.
- Comparison with stored correct answer
Stored correct answer: B
Our derived answer: B
So the answer matches the stored correct answer.
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