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P Block Elements question

2024 · 8 Apr · Shift 2 · Q19
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P Block Elements question

2024 · 8 Apr · Shift 2 · Q19

JEE MainChemistryP Block ElementsMCQ+4 / −1
Identify the incorrect statements about group 15 elements : (A) Dinitrogen is a diatomic gas which acts like an inert gas at room temperature. (B) The common oxidation states of these elements are −3,+3-3,+3−3,+3 and +5. (C) Nitrogen has unique ability to form pπ−pπ\mathrm{p} \pi-\mathrm{p} \pipπ−pπ multiple bonds. (D) The stability of +5 oxidation states increases down the group. (E) Nitrogen shows a maximum covalency of 6. Choose the correct answer from the options given below :
  1. A
    (A), (C), (E) only
  2. B
    (D) and (E) only
  3. C
    (A), (B), (D) only
  4. D
    (B), (D), (E) only
View written solutionFree

Correct answer: B

  1. Check each statement for group 15 elements

Group 15 elements are: N,P,As,Sb,Bi\mathrm{N, P, As, Sb, Bi}N,P,As,Sb,Bi.

Their common properties include oxidation states −3,+3,-3, +3,−3,+3, and +5+5+5, and down the group the inert pair effect becomes more significant.


  1. Statement (A): Dinitrogen is a diatomic gas which acts like an inert gas at room temperature.
  • N2\mathrm{N_2}N2​ is indeed a diatomic gas.
  • It is very unreactive at room temperature because of the strong triple bond, N≡N\mathrm{N\equiv N}N≡N.
  • So it behaves almost inert at room temperature.

Hence, (A) is correct.


  1. Statement (B): The common oxidation states of these elements are −3,+3-3,+3−3,+3 and +5+5+5.
  • This is a standard property of group 15 elements.
  • Nitrogen commonly shows −3,+3,+5-3, +3, +5−3,+3,+5.
  • Heavier members also commonly show +3+3+3 and +5+5+5.

Hence, (B) is correct.


  1. Statement (C): Nitrogen has unique ability to form pπ−pπ\mathrm{p}\pi-\mathrm{p}\pipπ−pπ multiple bonds.
  • Nitrogen, due to small size and high electronegativity, forms strong multiple bonds like: N≡N,C≡N,N=O\mathrm{N\equiv N},\quad \mathrm{C\equiv N},\quad \mathrm{N=O}N≡N,C≡N,N=O
  • This is indeed a characteristic feature of nitrogen.

Hence, (C) is correct.


  1. Statement (D): The stability of +5+5+5 oxidation states increases down the group.
  • Due to inert pair effect, the stability of the lower oxidation state +3+3+3 increases down the group.
  • Therefore, the stability of the higher oxidation state +5+5+5 decreases down the group.

So (D) is incorrect.


  1. Statement (E): Nitrogen shows a maximum covalency of 6.
  • Nitrogen is a second-period element.
  • It has no vacant ddd-orbitals and cannot expand its octet.
  • Therefore, its maximum covalency is 4, not 6.

So (E) is incorrect.


  1. Incorrect statements

The incorrect statements are: (D) and (E)\boxed{(D) \text{ and } (E)}(D) and (E)​

This corresponds to Option B.


  1. Comparison with stored correct answer

Stored correct answer: B

Our derived answer: B

So the answer matches the stored correct answer.

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