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P Block Elements question

2018 · Shift 0 · Q11
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P Block Elements question

2018 · Shift 0 · Q11

JEE MainChemistryP Block ElementsMCQ+4 / −1
The compound that does not produce nitrogen gas by the thermal decomposition is :
  1. A
    (NH4)2SO4(NH_4)_2SO_4(NH4​)2​SO4​
  2. B
    Ba(N3)2Ba(N_3)_2Ba(N3​)2​
  3. C
    (NH4)2Cr2O7(NH_4)_2Cr_2O_7(NH4​)2​Cr2​O7​
  4. D
    NH4NO2NH_4NO_2NH4​NO2​
View written solutionFree

Correct answer: A

  1. We check the thermal decomposition of each compound and see whether N2N_2N2​ gas is formed.

  2. Option A: (NH4)2SO4(NH_4)_2SO_4(NH4​)2​SO4​

On heating, ammonium sulfate does not give nitrogen gas. It mainly decomposes to products such as ammonia and acidic sulfate-related species, not N2N_2N2​.

So, this option does not produce N2N_2N2​.

  1. Option B: Ba(N3)2Ba(N_3)_2Ba(N3​)2​

N3−N_3^-N3−​ is the azide ion. Metal azides decompose on heating to give the metal and nitrogen gas:

Ba(N3)2→Ba+3N2Ba(N_3)_2 \rightarrow Ba + 3N_2Ba(N3​)2​→Ba+3N2​

So, this option does produce N2N_2N2​.

  1. Option C: (NH4)2Cr2O7(NH_4)_2Cr_2O_7(NH4​)2​Cr2​O7​

Ammonium dichromate decomposes as:

(NH4)2Cr2O7→Cr2O3+N2+4H2O(NH_4)_2Cr_2O_7 \rightarrow Cr_2O_3 + N_2 + 4H_2O(NH4​)2​Cr2​O7​→Cr2​O3​+N2​+4H2​O

So, this option does produce N2N_2N2​.

  1. Option D: NH4NO2NH_4NO_2NH4​NO2​

Ammonium nitrite decomposes as:

NH4NO2→N2+2H2ONH_4NO_2 \rightarrow N_2 + 2H_2ONH4​NO2​→N2​+2H2​O

So, this option does produce N2N_2N2​.

  1. Therefore, the only compound that does not produce nitrogen gas on thermal decomposition is:

(NH4)2SO4\boxed{(NH_4)_2SO_4}(NH4​)2​SO4​​

  1. Comparison with stored answer

Stored correct answer: A

Our derived answer: A

Hence, the derived answer agrees with the stored correct answer.

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