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P Block Elements question

2016 · 9 Apr · Shift 1 · Q14
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P Block Elements question

2016 · 9 Apr · Shift 1 · Q14

JEE MainChemistryP Block ElementsMCQ+4 / −1
The non-metal that does not exhibit positive oxidation state is :
  1. A
    Oxygen
  2. B
    Iodine
  3. C
    Chlorine
  4. D
    Fluorine
View written solutionFree

Correct answer: D

  1. We need the non-metal which does not show any positive oxidation state.

  2. Check each option:

    A. Oxygen
    Oxygen usually shows oxidation state −2-2−2, but in compounds with fluorine, it can show positive oxidation states:

    • In OF2\mathrm{OF_2}OF2​, oxygen is +2+2+2
    • In O2F2\mathrm{O_2F_2}O2​F2​, average oxidation state of oxygen is +1+1+1

    So, oxygen does exhibit positive oxidation state.

    B. Iodine
    Iodine shows several positive oxidation states such as +1,+3,+5,+7+1, +3, +5, +7+1,+3,+5,+7 in compounds like:

    • ICl\mathrm{ICl}ICl : iodine =+1= +1=+1
    • HIO3\mathrm{HIO_3}HIO3​ : iodine =+5= +5=+5
    • HIO4\mathrm{HIO_4}HIO4​ : iodine =+7= +7=+7

    So, iodine does exhibit positive oxidation states.

    C. Chlorine
    Chlorine also shows positive oxidation states such as +1,+3,+5,+7+1, +3, +5, +7+1,+3,+5,+7 in compounds like:

    • HOCl\mathrm{HOCl}HOCl : chlorine =+1= +1=+1
    • HClO3\mathrm{HClO_3}HClO3​ : chlorine =+5= +5=+5
    • HClO4\mathrm{HClO_4}HClO4​ : chlorine =+7= +7=+7

    So, chlorine does exhibit positive oxidation states.

    D. Fluorine
    Fluorine is the most electronegative element. Therefore, in all its compounds, it has oxidation state −1-1−1 (except elemental F2\mathrm{F_2}F2​ where it is 000). It never shows a positive oxidation state.

  3. Therefore, the correct answer is:

D: Fluorine\boxed{\text{D: Fluorine}}D: Fluorine​

  1. Comparison with stored correct answer:
  • Stored correct answer: D\text{D}D
  • Derived answer: D\text{D}D

Hence, they agree.

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