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P Block Elements question

2014 · Shift 0 · Q21
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P Block Elements question

2014 · Shift 0 · Q21

JEE MainChemistryP Block ElementsMCQ+4 / −1
Which one of the following properties is not shown by NO?
  1. A
    It combines with oxygen to form nitrogen dioxide
  2. B
    It’s bond order is 2.5
  3. C
    It is diamagnetic in gaseous state
  4. D
    It is a neutral oxide
View written solutionFree

Correct answer: C

  1. Identify the species:

    The compound is nitric oxide, NO\mathrm{NO}NO.

  2. Check each option:

    Option A: It combines with oxygen to form nitrogen dioxide

    This is true. 2NO+O2→2NO22\mathrm{NO} + \mathrm{O}_2 \rightarrow 2\mathrm{NO}_22NO+O2​→2NO2​ So NO does combine with oxygen to form NO2\mathrm{NO}_2NO2​.

    Option B: Its bond order is 2.52.52.5

    This is also true.

    Total valence electrons in NO: 5+6=115 + 6 = 115+6=11 Since NO has an odd number of electrons, it is a radical. From molecular orbital theory, NO has bond order: Bond order=Nb−Na2=2.5\text{Bond order} = \frac{N_b - N_a}{2} = 2.5Bond order=2Nb​−Na​​=2.5 So this statement is correct.

    Option C: It is diamagnetic in gaseous state

    This is false.

    NO has 11 valence electrons, so one electron remains unpaired in the molecular orbital configuration. Therefore, NO is paramagnetic, not diamagnetic.

    Option D: It is a neutral oxide

    This is true.

    NO is classified as a neutral oxide because it is neither acidic nor basic under normal conditions.

  3. Conclusion:

    The property not shown by NO is: C\boxed{\text{C}}C​

    because NO is paramagnetic, not diamagnetic.

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