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P Block Elements question

2014 · Shift 0 · Q20
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P Block Elements question

2014 · Shift 0 · Q20

JEE MainChemistryP Block ElementsMCQ+4 / −1
The correct statement for the molecule, CsI3CsI_3CsI3​ is :
  1. A
    it contains Cs3+Cs^{3+}Cs3+ and I−I^-I− ions.
  2. B
    it contains Cs+Cs^+Cs+, I−I^-I− and lattice I2I_2I2​ molecule.
  3. C
    it is a covalent molecule
  4. D
    it contains Cs+Cs^+Cs+ and I3−I_3^-I3−​ ions
View written solutionFree

Correct answer: D

  1. Identify the type of compound

    CsCsCs is an alkali metal, so it almost always forms the ion Cs+Cs^+Cs+.

    Therefore, option A is immediately suspicious because Cs3+Cs^{3+}Cs3+ is not a stable/common oxidation state for cesium.

  2. Interpret the formula CsI3CsI_3CsI3​

    Since cesium forms Cs+Cs^+Cs+, the remaining part must carry a charge of −1-1−1:

    CsI3=Cs++(I3)−CsI_3 = Cs^+ + (I_3)^-CsI3​=Cs++(I3​)−

    So the species present is the polyhalide ion I3−I_3^-I3−​, called the triiodide ion.

  3. Nature of polyhalide salts

    Compounds like KI3KI_3KI3​, CsI3CsI_3CsI3​ etc. are known as polyhalide salts. They are ionic solids containing:

    M++I3−M^+ + I_3^-M++I3−​

    where M+M^+M+ is an alkali metal cation.

  4. Check each option

    A: "it contains Cs3+Cs^{3+}Cs3+ and I−I^-I− ions"
    This is incorrect because cesium does not form stable Cs3+Cs^{3+}Cs3+ in such compounds.

    B: "it contains Cs+Cs^+Cs+, I−I^-I− and lattice I2I_2I2​ molecule"
    Although I3−I_3^-I3−​ can be conceptually viewed as I−+I2I^- + I_2I−+I2​, the actual ionic species in the crystal is represented as I3−I_3^-I3−​. Hence this is not the best/correct description for the compound.

    C: "it is a covalent molecule"
    Incorrect. CsI3CsI_3CsI3​ is an ionic polyhalide salt.

    D: "it contains Cs+Cs^+Cs+ and I3−I_3^-I3−​ ions"
    This is correct.

  5. Final answer

    The correct statement is:

    D: it contains Cs+ and I3− ions\boxed{\text{D: it contains } Cs^+ \text{ and } I_3^- \text{ ions}}D: it contains Cs+ and I3−​ ions​

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