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Electrochemistry question

2025 · 8 Apr · Shift 2 · Q21
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Electrochemistry question

2025 · 8 Apr · Shift 2 · Q21

JEE MainChemistryElectrochemistryNumerical+4 / −1
Consider the following half cell reaction Cr2O72− (aq)+6e−+14H+ (aq)→2Cr3+ (aq)+7H2O (ℓ)\text{Cr}_2\text{O}_7^{2-} \, (\text{aq}) + 6\text{e}^- + 14\text{H}^+ \, (\text{aq}) \rightarrow 2\text{Cr}^{3+} \, (\text{aq}) + 7\text{H}_2\text{O} \, (\ell)Cr2​O72−​(aq)+6e−+14H+(aq)→2Cr3+(aq)+7H2​O(ℓ) The reaction was conducted with the ratio of [Cr3+]2[Cr2O72−]=10−6\frac{[\text{Cr}^{3+}]^2}{[\text{Cr}_2\text{O}_7^{2-}]} = 10^{-6}[Cr2​O72−​][Cr3+]2​=10−6. The pH value at which the EMF of the half cell will become zero is ‾\underline{\hspace{2cm}}​. (nearest integer value) [Given: standard half cell reduction potential ECr2O72−,H+/Cr3+∘=1.33 VE^{\circ}_{\text{Cr}_2\text{O}_7^{2-}, \text{H}^+/\text{Cr}^{3+}} = 1.33\, \text{V}ECr2​O72−​,H+/Cr3+∘​=1.33V, 2.303RTF=0.059 V\frac{2.303RT}{F} = 0.059\, \text{V}F2.303RT​=0.059V.]
Numerical answer
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