JEE MainChemistryElectrochemistryNumerical+4 / −1
The magnitude of the change in oxidising power of the couple is x 10 4 V, if the concentration is decreased from 1M to 10 4 M at 25 C. (Assume concentration of and to be same on change in concentration). The value of x is .
Numerical answer
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Correct answer: 3776
- Write the relevant reduction half-reaction
For the couple in acidic medium:
- Write the Nernst equation
For the reduction potential,
Given that the concentrations of and remain the same, only changes. So the change in potential depends only on the term.
- Find the change in potential when changes
Initially,
Finally,
Using the Nernst equation, the change in reduction potential is:
Since only changes,
This can be written as
Hence,
Now,
So,
Thus, the magnitude of change in oxidising power is
- Match with the given form
The question states magnitude .
So,
- Final answer
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