JEE MainChemistryElectrochemistryNumerical+4 / −1
Assume a cell with the following reaction V Ecell for the above reaction is V. (Nearest integer) [Given : log 2.5 = 0.3979, T = 298 K]
Numerical answer
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Correct answer: 3
- Write the cell reaction and identify
Given reaction:
Here, copper is oxidized:
Silver ion is reduced:
So, the number of electrons transferred is:
- Use the Nernst equation
For the reaction,
At , with :
- Calculate the reaction quotient
For
Solids are omitted, so
Substitute the given concentrations:
- Evaluate
- Substitute into Nernst equation
So,
Thus,
- Nearest integer
Therefore, the required nearest integer is 3.
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