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D and F Block Elements question

2025 · 29 Jan · Shift 1 · Q21
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D and F Block Elements question

2025 · 29 Jan · Shift 1 · Q21

JEE MainChemistryD and F Block ElementsNumerical+4 / −1
The molar mass of the water insoluble product formed from the fusion of chromite ore (FeCr₂O₄) with Na₂CO₃ in presence of O₂ is ‾\underline{\hspace{2cm}}​ g mol⁻¹.
Numerical answer
View written solutionFree

Correct answer: 160

  1. Identify the reaction during fusion of chromite ore

Chromite ore is FeCr2O4\mathrm{FeCr_2O_4}FeCr2​O4​. On fusion with Na2CO3\mathrm{Na_2CO_3}Na2​CO3​ in presence of O2\mathrm{O_2}O2​, chromium is oxidized to chromate and iron is converted to ferric oxide.

A commonly written balanced reaction is:

4FeCr2O4+8Na2CO3+7O2→8Na2CrO4+2Fe2O3+8CO24\mathrm{FeCr_2O_4} + 8\mathrm{Na_2CO_3} + 7\mathrm{O_2} \rightarrow 8\mathrm{Na_2CrO_4} + 2\mathrm{Fe_2O_3} + 8\mathrm{CO_2}4FeCr2​O4​+8Na2​CO3​+7O2​→8Na2​CrO4​+2Fe2​O3​+8CO2​
  1. Find the water-insoluble product

In this reaction:

  • Na2CrO4\mathrm{Na_2CrO_4}Na2​CrO4​ is water soluble.
  • Fe2O3\mathrm{Fe_2O_3}Fe2​O3​ is water insoluble.

So the required water-insoluble product is ferric oxide, Fe2O3\mathrm{Fe_2O_3}Fe2​O3​.

  1. Calculate its molar mass

Using atomic masses:

  • Fe=56\mathrm{Fe} = 56Fe=56
  • O=16\mathrm{O} = 16O=16

Therefore,

M(Fe2O3)=2(56)+3(16)M(\mathrm{Fe_2O_3}) = 2(56) + 3(16)M(Fe2​O3​)=2(56)+3(16) =112+48=160 g mol−1= 112 + 48 = 160\ \text{g mol}^{-1}=112+48=160 g mol−1
  1. Final answer

The molar mass of the water-insoluble product is:

160\boxed{160}160​
  1. Comparison with stored answer

Stored correct answer = 160160160

Our derived answer also = 160160160, so they agree.

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