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D and F Block Elements question

2025 · 28 Jan · Shift 2 · Q9
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D and F Block Elements question

2025 · 28 Jan · Shift 2 · Q9

JEE MainChemistryD and F Block ElementsMCQ+4 / −1
The amphoteric oxide among V2O3, V2O4\mathrm{V}_2 \mathrm{O}_3, \mathrm{~V}_2 \mathrm{O}_4V2​O3​, V2​O4​ and V2O5\mathrm{V}_2 \mathrm{O}_5V2​O5​, upon reaction with alkali leads to formation of an oxide anion. The oxidation state of V in the oxide anion is :
  1. A
    + 4
  2. B
    + 5
  3. C
    + 3
  4. D
    + 7
View written solutionFree

Correct answer: B

  1. Identify the amphoteric oxide among the given vanadium oxides

    The oxidation states of vanadium are:

    • In V2O3\mathrm{V_2O_3}V2​O3​: 2x+3(−2)=0⇒x=+32x+3(-2)=0 \Rightarrow x=+32x+3(−2)=0⇒x=+3
    • In V2O4\mathrm{V_2O_4}V2​O4​: 2x+4(−2)=0⇒x=+42x+4(-2)=0 \Rightarrow x=+42x+4(−2)=0⇒x=+4
    • In V2O5\mathrm{V_2O_5}V2​O5​: 2x+5(−2)=0⇒x=+52x+5(-2)=0 \Rightarrow x=+52x+5(−2)=0⇒x=+5

    In general:

    • Lower oxidation state oxides are more basic
    • Higher oxidation state oxides are more acidic
    • Intermediate oxidation state oxides are often amphoteric

    Therefore:

    • V2O3\mathrm{V_2O_3}V2​O3​ is mainly basic
    • V2O5\mathrm{V_2O_5}V2​O5​ is acidic
    • V2O4\mathrm{V_2O_4}V2​O4​ is amphoteric
  2. Reaction of amphoteric oxide with alkali

    Since V2O4\mathrm{V_2O_4}V2​O4​ is amphoteric, it reacts with alkali to form an oxoanion (oxide anion of vanadium), namely vanadate-type species.

    On oxidation/alkaline treatment, vanadium forms vanadate ion where vanadium is in the +5+5+5 oxidation state, such as VO43−\mathrm{VO_4^{3-}}VO43−​ or related oxoanions.

  3. Find oxidation state of V in the oxide anion

    For example, in VO43−\mathrm{VO_4^{3-}}VO43−​: x+4(−2)=−3x+4(-2)=-3x+4(−2)=−3 x−8=−3x-8=-3x−8=−3 x=+5x=+5x=+5

    Hence, the oxidation state of V in the oxide anion formed is +5+5+5.

  4. Check options

    • A: +4+4+4 ❌
    • B: +5+5+5 ✅
    • C: +3+3+3 ❌
    • D: +7+7+7 ❌

Therefore, the correct answer is B.

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