JEE MainChemistryD and F Block ElementsMCQ+4 / −1
The amphoteric oxide among and , upon reaction with alkali leads to formation of an oxide anion. The oxidation state of V in the oxide anion is :
- A+ 4
- B+ 5
- C+ 3
- D+ 7
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Correct answer: B
-
Identify the amphoteric oxide among the given vanadium oxides
The oxidation states of vanadium are:
- In :
- In :
- In :
In general:
- Lower oxidation state oxides are more basic
- Higher oxidation state oxides are more acidic
- Intermediate oxidation state oxides are often amphoteric
Therefore:
- is mainly basic
- is acidic
- is amphoteric
-
Reaction of amphoteric oxide with alkali
Since is amphoteric, it reacts with alkali to form an oxoanion (oxide anion of vanadium), namely vanadate-type species.
On oxidation/alkaline treatment, vanadium forms vanadate ion where vanadium is in the oxidation state, such as or related oxoanions.
-
Find oxidation state of V in the oxide anion
For example, in :
Hence, the oxidation state of V in the oxide anion formed is .
-
Check options
- A: ❌
- B: ✅
- C: ❌
- D: ❌
Therefore, the correct answer is B.
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