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D and F Block Elements question

2025 · 22 Jan · Shift 2 · Q23
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D and F Block Elements question

2025 · 22 Jan · Shift 2 · Q23

JEE MainChemistryD and F Block ElementsNumerical+4 / −1
Niobium (Nb)(\mathrm{Nb})(Nb) and ruthenium (Ru)(\mathrm{Ru})(Ru) have "xxx" and "yyy" number of electrons in their respective 4 d orbitals. The value of x+yx+yx+y is ‾\underline{\hspace{2cm}}​.
Numerical answer
View written solutionFree

Correct answer: 11

  1. We need the number of electrons present in the 4d4d4d orbitals of:

    • Niobium (Nb)(\mathrm{Nb})(Nb)
    • Ruthenium (Ru)(\mathrm{Ru})(Ru)
  2. Write their atomic numbers:

    • Nb:Z=41\mathrm{Nb}: Z=41Nb:Z=41
    • Ru:Z=44\mathrm{Ru}: Z=44Ru:Z=44
  3. Find their ground-state electronic configurations.

    For niobium (Nb)(\mathrm{Nb})(Nb): The expected filling is near [Kr] 5s24d3[\mathrm{Kr}]\,5s^2 4d^3[Kr]5s24d3, but due to stability, the actual configuration is Nb=[Kr] 4d45s1\mathrm{Nb} = [\mathrm{Kr}]\,4d^4 5s^1Nb=[Kr]4d45s1 Hence, the number of electrons in 4d4d4d orbitals is x=4x=4x=4

    For ruthenium (Ru)(\mathrm{Ru})(Ru): Its actual ground-state configuration is Ru=[Kr] 4d75s1\mathrm{Ru} = [\mathrm{Kr}]\,4d^7 5s^1Ru=[Kr]4d75s1 Hence, the number of electrons in 4d4d4d orbitals is y=7y=7y=7

  4. Therefore, x+y=4+7=11x+y=4+7=11x+y=4+7=11

  5. Final answer: 11\boxed{11}11​

  6. Comparison with stored correct answer: Stored correct answer = 111111. Our derived answer also = 111111. Therefore, they agree.

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