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D and F Block Elements question

2022 · 25 Jun · Shift 1 · Q6
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D and F Block Elements question

2022 · 25 Jun · Shift 1 · Q6

JEE MainChemistryD and F Block ElementsMCQ+4 / −1
Among the following, which is the strongest oxidizing agent?
  1. A
    Mn3+Mn^{3+}Mn3+
  2. B
    Fe3+Fe^{3+}Fe3+
  3. C
    Ti3+Ti^{3+}Ti3+
  4. D
    Cr3+Cr^{3+}Cr3+
View written solutionFree

Correct answer: A

  1. Idea: The strongest oxidizing agent is the species that is most easily reduced.

    So we compare the reduction tendencies of: Mn3+,  Fe3+,  Ti3+,  Cr3+Mn^{3+},\; Fe^{3+},\; Ti^{3+},\; Cr^{3+}Mn3+,Fe3+,Ti3+,Cr3+

    Each acts as an oxidizing agent by gaining electrons: M3++e−→M2+M^{3+} + e^- \rightarrow M^{2+}M3++e−→M2+

  2. Use standard reduction potentials for the couples M3+/M2+M^{3+}/M^{2+}M3+/M2+:

    • Mn3++e−→Mn2+,E∘=+1.51 VMn^{3+} + e^- \rightarrow Mn^{2+}, \quad E^\circ = +1.51\,VMn3++e−→Mn2+,E∘=+1.51V
    • Fe3++e−→Fe2+,E∘=+0.77 VFe^{3+} + e^- \rightarrow Fe^{2+}, \quad E^\circ = +0.77\,VFe3++e−→Fe2+,E∘=+0.77V
    • Cr3++e−→Cr2+,E∘=−0.41 VCr^{3+} + e^- \rightarrow Cr^{2+}, \quad E^\circ = -0.41\,VCr3++e−→Cr2+,E∘=−0.41V
    • Ti3++e−→Ti2+,E∘≈−0.37 VTi^{3+} + e^- \rightarrow Ti^{2+}, \quad E^\circ \approx -0.37\,VTi3++e−→Ti2+,E∘≈−0.37V
  3. Criterion: Larger, more positive E∘E^\circE∘ means greater tendency to get reduced, hence stronger oxidizing agent.

  4. Comparison: Mn3+>Fe3+>Ti3+,Cr3+Mn^{3+} > Fe^{3+} > Ti^{3+}, Cr^{3+}Mn3+>Fe3+>Ti3+,Cr3+ in oxidizing strength.

  5. Conclusion: The strongest oxidizing agent is Mn3+\boxed{Mn^{3+}}Mn3+​

  6. Option check:

    • A: Mn3+Mn^{3+}Mn3+ — Correct
    • B: Fe3+Fe^{3+}Fe3+ — Weaker than Mn3+Mn^{3+}Mn3+
    • C: Ti3+Ti^{3+}Ti3+ — Not strong oxidizing agent
    • D: Cr3+Cr^{3+}Cr3+ — Not strong oxidizing agent
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