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D and F Block Elements question

2021 · 17 Mar · Shift 2 · Q18
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D and F Block Elements question

2021 · 17 Mar · Shift 2 · Q18

JEE MainChemistryD and F Block ElementsNumerical+4 / −1
In the ground state of atomic Fe(Z = 26), the spin-only magnetic moment is ‾×\underline{\hspace{2cm}}\times​× 10 −-− 1 BM. (Round off to the Nearest Integer). [Given : 3\sqrt 33​= 1.73, 2\sqrt 22​ = 1.41 ]
Numerical answer
View written solutionFree

Correct answer: 49

  1. Write the electronic configuration of Fe (Z=26Z=26Z=26)

    Ground state configuration of iron is Fe:[Ar] 3d6 4s2\mathrm{Fe}: [\mathrm{Ar}]\,3d^6\,4s^2Fe:[Ar]3d64s2

  2. Find the number of unpaired electrons

    In 3d63d^63d6, the five ddd orbitals are filled according to Hund’s rule:

    • first 5 electrons occupy 5 orbitals singly
    • the 6th electron pairs in one orbital

    So, number of unpaired electrons: n=4n = 4n=4

  3. Use spin-only magnetic moment formula

    μ=n(n+2) BM\mu = \sqrt{n(n+2)}\,\text{BM}μ=n(n+2)​BM

    Substituting n=4n=4n=4: μ=4(4+2)=24=26 BM\mu = \sqrt{4(4+2)} = \sqrt{24} = 2\sqrt{6}\,\text{BM}μ=4(4+2)​=24​=26​BM

  4. Numerical evaluation

    6=3⋅2≈1.73×1.41=2.4393\sqrt{6} = \sqrt{3}\cdot\sqrt{2} \approx 1.73 \times 1.41 = 2.43936​=3​⋅2​≈1.73×1.41=2.4393

    Therefore, μ=2×2.4393=4.8786 BM\mu = 2\times 2.4393 = 4.8786\,\text{BM}μ=2×2.4393=4.8786BM

  5. Match with the required form

    The question asks for: ‾×10−1 BM\underline{\hspace{1cm}} \times 10^{-1}\,\text{BM}​×10−1BM

    Since 4.8786 BM=48.786×10−1 BM4.8786\,\text{BM} = 48.786 \times 10^{-1}\,\text{BM}4.8786BM=48.786×10−1BM

    Rounding to the nearest integer: 494949

  6. Final answer

    49\boxed{49}49​

  7. Comparison with stored answer

    Stored correct answer = 494949

    This matches the derived answer.

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