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D and F Block Elements question

2016 · Shift 0 · Q7
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D and F Block Elements question

2016 · Shift 0 · Q7

JEE MainChemistryD and F Block ElementsMCQ+4 / −1
The reaction of zinc with dilute and concentrated nitric acid, respectively, produces :
  1. A
    NO2NO_2NO2​ and NONONO
  2. B
    NONONO and N2ON_2ON2​O
  3. C
    NO2NO_2NO2​ and N2ON_2ON2​O
  4. D
    N2ON_2ON2​O and NO2NO_2NO2​
View written solutionFree

Correct answer: D

  1. Key idea: Nitric acid is an oxidizing acid, so with metals like zinc, hydrogen gas is generally not evolved. Instead, nitric acid is reduced to different nitrogen oxides depending on its concentration.

  2. Reaction with dilute nitric acid: For zinc, with dilute HNO3HNO_3HNO3​, the reduction product is typically nitrous oxide N2ON_2ON2​O.

    A representative reaction is: 4Zn+10HNO3(dil.)→4Zn(NO3)2+N2O+5H2O4Zn + 10HNO_3(\text{dil.}) \rightarrow 4Zn(NO_3)_2 + N_2O + 5H_2O4Zn+10HNO3​(dil.)→4Zn(NO3​)2​+N2​O+5H2​O

    So, with dilute nitric acid, zinc produces: N2ON_2ON2​O

  3. Reaction with concentrated nitric acid: With concentrated HNO3HNO_3HNO3​, nitric acid is reduced mainly to nitrogen dioxide NO2NO_2NO2​.

    A representative reaction is: Zn+4HNO3(conc.)→Zn(NO3)2+2NO2+2H2OZn + 4HNO_3(\text{conc.}) \rightarrow Zn(NO_3)_2 + 2NO_2 + 2H_2OZn+4HNO3​(conc.)→Zn(NO3​)2​+2NO2​+2H2​O

    So, with concentrated nitric acid, zinc produces: NO2NO_2NO2​

  4. Match with the options: The question asks for products with dilute and concentrated nitric acid, respectively:

    • Dilute HNO3→N2OHNO_3 \rightarrow N_2OHNO3​→N2​O
    • Concentrated HNO3→NO2HNO_3 \rightarrow NO_2HNO3​→NO2​

    Therefore the correct option is: D: N2O and NO2\boxed{\text{D: } N_2O \text{ and } NO_2}D: N2​O and NO2​​

  5. Comparison with stored answer: Stored correct answer = D

    Our derived answer = D

    Hence, they agree.

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