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D and F Block Elements question

2015 · Shift 0 · Q9
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D and F Block Elements question

2015 · Shift 0 · Q9

JEE MainChemistryD and F Block ElementsMCQ+4 / −1
Match the catalysts to the correct processes :

Catalyst Process
(A) TiCl3 (i) Wacker process
(B) PdCl2 (ii) Ziegler - Natta
polymerization
(C) CuCl2 (iii) Contact process
(D) V2O5 (iv) Deacon's process
  1. A
    (A)−(ii),  (B)−(iii),  (C)−(iv),  (D)−(i)\left( A \right) - \left( {ii} \right),\,\,\left( B \right) - \left( {iii} \right),\,\,\left( C \right) - \left( {iv} \right),\,\,\left( D \right) - \left( i \right)(A)−(ii),(B)−(iii),(C)−(iv),(D)−(i)
  2. B
    (A)−(iii),  (B)−(i),  (C)−(ii),  (D)−(iv)\left( A \right) - \left( {iii} \right),\,\,\left( B \right) - \left( i \right),\,\,\left( C \right) - \left( {ii} \right),\,\,\left( D \right) - \left( {iv} \right)(A)−(iii),(B)−(i),(C)−(ii),(D)−(iv)
  3. C
    (A)−(iii),  (B)−(ii),  (C)−(iv),  (D)−(i)\left( A \right) - \left( {iii} \right),\,\,\left( B \right) - \left( {ii} \right),\,\,\left( C \right) - \left( {iv} \right),\,\,\left( D \right) - \left( i \right)(A)−(iii),(B)−(ii),(C)−(iv),(D)−(i)
  4. D
    (A)−(ii),  (B)−(i),  (C)−(iv),  (D)−(iii)\left( A \right) - \left( {ii} \right),\,\,\left( B \right) - \left( i \right),\,\,\left( C \right) - \left( {iv} \right),\,\,\left( D \right) - \left( {iii} \right)(A)−(ii),(B)−(i),(C)−(iv),(D)−(iii)
View written solutionFree

Correct answer: D

  1. We match each catalyst with its well-known industrial process.

  2. Identify each catalyst-process pair:

    (A) TiCl3\mathrm{TiCl_3}TiCl3​

    • This is associated with Ziegler–Natta polymerization.
    • So, A→(ii)A \to (ii)A→(ii)

    (B) PdCl2\mathrm{PdCl_2}PdCl2​

    • This is used in the Wacker process.
    • So, B→(i)B \to (i)B→(i)

    (C) CuCl2\mathrm{CuCl_2}CuCl2​

    • This is used in Deacon's process.
    • So, C→(iv)C \to (iv)C→(iv)

    (D) V2O5\mathrm{V_2O_5}V2​O5​

    • This is the catalyst in the Contact process.
    • So, D→(iii)D \to (iii)D→(iii)
  3. Therefore, the complete matching is:

(A)−(ii),(B)−(i),(C)−(iv),(D)−(iii)(A)-(ii),\quad (B)-(i),\quad (C)-(iv),\quad (D)-(iii)(A)−(ii),(B)−(i),(C)−(iv),(D)−(iii)
  1. Compare with the given options:
  • This matches Option D.
  1. Comparison with stored correct answer:
  • Stored correct answer = D
  • Derived answer = D
  • Hence, they agree.
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