JEE MainChemistryCoordination CompoundsMCQ+4 / −1
'X' is the number of acidic oxides among , , , and . The primary valency of cobalt in is Y. The value of X + Y is .
- A3
- B4
- C2
- D5
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Correct answer: 6
- Find : number of acidic oxides
We examine each oxide:
- : vanadium is in oxidation state. This oxide is amphoteric.
- : vanadium is in oxidation state. Lower oxidation state metal oxides are generally basic.
- : chromium is in oxidation state. This is an acidic oxide.
- : vanadium is in oxidation state. This is an acidic oxide.
- : manganese is in oxidation state. This is the anhydride of permanganic acid, so it is acidic.
Hence, acidic oxides are: So,
- Find : primary valency of cobalt in
Here, is ethylenediamine (en), which is a neutral ligand.
Let oxidation state of Co be .
For one complex cation: Since is neutral, charge on complex equals oxidation state of Co.
The full compound is: Each sulfate ion has charge , so total negative charge is: Thus total positive charge of the two complex ions must be . So each complex ion has charge: Therefore cobalt is in oxidation state:
Since primary valency = oxidation state, we get
- Calculate
- Compare with given options
The computed value is: But the options are only. So none of the listed options matches.
- Compare with stored correct answer
Stored correct answer is D = 5, but our derived answer is 6.
Therefore, the stored answer appears to be incorrect.
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