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Coordination Compounds question

2025 · 7 Apr · Shift 2 · Q19
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Coordination Compounds question

2025 · 7 Apr · Shift 2 · Q19

JEE MainChemistryCoordination CompoundsMCQ+4 / −1
'X' is the number of acidic oxides among VO2VO_2VO2​, V2O3V_2O_3V2​O3​, CrO3CrO_3CrO3​, V2O5V_2O_5V2​O5​ and Mn2O7Mn_2O_7Mn2​O7​. The primary valency of cobalt in [Co(H2NCH2CH2NH2)3]2(SO4)3[Co(H_2NCH_2CH_2NH_2)_3]_2(SO_4)_3[Co(H2​NCH2​CH2​NH2​)3​]2​(SO4​)3​ is Y. The value of X + Y is ‾\underline{\hspace{2cm}}​.
  1. A
    3
  2. B
    4
  3. C
    2
  4. D
    5
View written solutionFree

Correct answer: 6

  1. Find XXX: number of acidic oxides

We examine each oxide:

  • VO2VO_2VO2​ : vanadium is in +4+4+4 oxidation state. This oxide is amphoteric.
  • V2O3V_2O_3V2​O3​ : vanadium is in +3+3+3 oxidation state. Lower oxidation state metal oxides are generally basic.
  • CrO3CrO_3CrO3​ : chromium is in +6+6+6 oxidation state. This is an acidic oxide.
  • V2O5V_2O_5V2​O5​ : vanadium is in +5+5+5 oxidation state. This is an acidic oxide.
  • Mn2O7Mn_2O_7Mn2​O7​ : manganese is in +7+7+7 oxidation state. This is the anhydride of permanganic acid, so it is acidic.

Hence, acidic oxides are: CrO3, V2O5, Mn2O7CrO_3,\ V_2O_5,\ Mn_2O_7CrO3​, V2​O5​, Mn2​O7​ So, X=3X=3X=3


  1. Find YYY: primary valency of cobalt in [Co(H2NCH2CH2NH2)3]2(SO4)3[Co(H_2NCH_2CH_2NH_2)_3]_2(SO_4)_3[Co(H2​NCH2​CH2​NH2​)3​]2​(SO4​)3​

Here, H2NCH2CH2NH2H_2NCH_2CH_2NH_2H2​NCH2​CH2​NH2​ is ethylenediamine (en), which is a neutral ligand.

Let oxidation state of Co be xxx.

For one complex cation: [Co(en)3]n+[Co(en)_3]^{n+}[Co(en)3​]n+ Since enenen is neutral, charge on complex equals oxidation state of Co.

The full compound is: [Co(en)3]2(SO4)3[Co(en)_3]_2(SO_4)_3[Co(en)3​]2​(SO4​)3​ Each sulfate ion has charge −2-2−2, so total negative charge is: 3×(−2)=−63\times(-2)=-63×(−2)=−6 Thus total positive charge of the two complex ions must be +6+6+6. So each complex ion has charge: +3+3+3 Therefore cobalt is in oxidation state: Y=3Y=3Y=3

Since primary valency = oxidation state, we get Y=3Y=3Y=3


  1. Calculate X+YX+YX+Y

X+Y=3+3=6X+Y=3+3=6X+Y=3+3=6


  1. Compare with given options

The computed value is: 666 But the options are 2,3,4,52,3,4,52,3,4,5 only. So none of the listed options matches.


  1. Compare with stored correct answer

Stored correct answer is D = 5, but our derived answer is 6.

Therefore, the stored answer appears to be incorrect.

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