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Correct answer: 2
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Identify the product complex
Ferric chloride reacts with oxalic acid / oxalate in presence of base to form the ferrioxalate complex.
Oxalic acid gives oxalate ion , which is a bidentate ligand.
Iron is in the oxidation state, so the complex formed is:
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Geometry of the complex
Since there are three bidentate oxalate ligands, the coordination number is .
Hence the complex has octahedral geometry.
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Optical activity check
The complex is of type: where is a symmetrical bidentate ligand.
Such octahedral complexes exist as two non-superimposable mirror images:
Therefore, the complex shows optical isomerism.
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Count of optical isomers
For an octahedral complex of type , the number of optical isomers is:
So, the iron complex exhibits 2 optical isomers.
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