JEE MainChemistryCoordination CompoundsNumerical+4 / −1
The homoleptic and octahedral complex of and has unpaired electron(s) in the set of orbitals.
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Correct answer: 1
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The complex described is the homoleptic octahedral aqua complex of cobalt(II):
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Determine the electronic configuration of .
Cobalt has atomic number :
For , remove two electrons from first:
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In an octahedral field, the -orbitals split into:
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Since is a weak field ligand, the complex is high spin.
So for high-spin octahedral configuration:
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Now place 5 electrons in the three orbitals according to Hund's rule:
First three electrons occupy singly:
The next two pair up in two of them:
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Therefore, in the set, there is exactly 1 unpaired electron.
Hence, the required number of unpaired electrons in the set is:
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