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Coordination Compounds question

2023 · 15 Apr · Shift 1 · Q22
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Coordination Compounds question

2023 · 15 Apr · Shift 1 · Q22

JEE MainChemistryCoordination CompoundsNumerical+4 / −1
The homoleptic and octahedral complex of Co2+\mathrm{Co}^{2+}Co2+ and H2O\mathrm{H}_{2} \mathrm{O}H2​O has ‾\underline{\hspace{2cm}}​ unpaired electron(s) in the t2gt_{2\mathrm{g}}t2g​ set of orbitals.
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Correct answer: 1

  1. The complex described is the homoleptic octahedral aqua complex of cobalt(II): [Co(H2O)6]2+[\mathrm{Co}(\mathrm{H_2O})_6]^{2+}[Co(H2​O)6​]2+

  2. Determine the electronic configuration of Co2+\mathrm{Co}^{2+}Co2+.

    Cobalt has atomic number 272727: Co:[Ar] 3d74s2\mathrm{Co}: [\mathrm{Ar}]\,3d^7 4s^2Co:[Ar]3d74s2

    For Co2+\mathrm{Co}^{2+}Co2+, remove two electrons from 4s4s4s first: Co2+:[Ar] 3d7\mathrm{Co}^{2+}: [\mathrm{Ar}]\,3d^7Co2+:[Ar]3d7

  3. In an octahedral field, the ddd-orbitals split into: t2g (lower energy)andeg (higher energy)t_{2g} \text{ (lower energy)} \quad \text{and} \quad e_g \text{ (higher energy)}t2g​ (lower energy)andeg​ (higher energy)

  4. Since H2O\mathrm{H_2O}H2​O is a weak field ligand, the complex is high spin.

    So for d7d^7d7 high-spin octahedral configuration: t2g5eg2t_{2g}^5 e_g^2t2g5​eg2​

  5. Now place 5 electrons in the three t2gt_{2g}t2g​ orbitals according to Hund's rule:

    First three electrons occupy singly: ↑↑↑\uparrow\quad \uparrow\quad \uparrow↑↑↑

    The next two pair up in two of them: ↑↓↑↓↑\uparrow\downarrow \quad \uparrow\downarrow \quad \uparrow↑↓↑↓↑

  6. Therefore, in the t2gt_{2g}t2g​ set, there is exactly 1 unpaired electron.

Hence, the required number of unpaired electrons in the t2gt_{2g}t2g​ set is: 1\boxed{1}1​

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