Sign in
12thPass logo
New chatPYQ LibraryDoubtsRank report
Sign in to see Recents

Your guest activity stays on this device

Sign in to save progress →
Sign in

Coordination Compounds question

2023 · 24 Jan · Shift 1 · Q22
Guest · filters and generic practice availableBrowsing as a guest · PYQ filters and generic practice are available. Sign in only for personalised features and saved progress.
  1. PYQ Library
  2. /JEE Main
  3. /Chemistry
  4. /Coordination Compounds
  5. /2023 · 24 Jan · Shift 1 · Q22

Coordination Compounds question

2023 · 24 Jan · Shift 1 · Q22

JEE MainChemistryCoordination CompoundsNumerical+4 / −1
The d-electronic configuration of [CoCl4]2−\mathrm{[CoCl_4]^{2-}}[CoCl4​]2− in tetrahedral crystal field in emt2n{e^mt_2^n}emt2n​. Sum of "m" and "number of unpaired electrons" is ‾\underline{\hspace{2cm}}​
Numerical answer
View written solutionFree

Correct answer: 7

  1. Find oxidation state of Co in [CoCl4]2−[\mathrm{CoCl_4}]^{2-}[CoCl4​]2−

Let oxidation state of Co be xxx.

x+4(−1)=−2x + 4(-1) = -2x+4(−1)=−2 x−4=−2x - 4 = -2x−4=−2 x=+2x = +2x=+2

So, cobalt is Co2+\mathrm{Co^{2+}}Co2+.

  1. Write the d-electron count of Co2+\mathrm{Co^{2+}}Co2+

Atomic number of Co is 272727.

Neutral Co: Co:[Ar] 3d74s2\mathrm{Co}: [Ar] \, 3d^7 4s^2Co:[Ar]3d74s2

For Co2+\mathrm{Co^{2+}}Co2+, remove two electrons from 4s4s4s first: Co2+:[Ar] 3d7\mathrm{Co^{2+}}: [Ar] \, 3d^7Co2+:[Ar]3d7

So the ion has 7 d-electrons.

  1. Tetrahedral crystal field splitting

In a tetrahedral field, the lower energy set is eee and the higher energy set is t2t_2t2​.

Thus, electrons fill as: emt2ne^m t_2^nemt2n​

Since tetrahedral complexes are generally high spin (because Δt\Delta_tΔt​ is small), for d7d^7d7 the arrangement is:

  • First fill lower eee set: 444 electrons maximum
  • Then fill higher t2t_2t2​ set with remaining 333 electrons

So, e4t23e^4 t_2^3e4t23​

Hence, m=4m = 4m=4

  1. Find number of unpaired electrons

For tetrahedral d7d^7d7:

  • In e4e^4e4, both orbitals are fully paired ⇒0\Rightarrow 0⇒0 unpaired there
  • In t23t_2^3t23​, the three electrons occupy three orbitals singly ⇒3\Rightarrow 3⇒3 unpaired electrons

Therefore, number of unpaired electrons =3= 3=3.

  1. Required sum

m+number of unpaired electrons=4+3=7m + \text{number of unpaired electrons} = 4 + 3 = 7m+number of unpaired electrons=4+3=7

Final Answer

7\boxed{7}7​

The derived answer matches the stored correct answer.

PreviousNext

More from Coordination Compounds

  • The hybridization and magnetic behaviour of cobalt ion in [Co(NH3​)6​]3+ complex, respectively is :2023 · MCQ
  • Which of the following cannot be explained by crystal field theory?2023 · MCQ
  • The number of paramagnetic species from the following is ​. [Ni(CN)4​]2−,[Ni(CO)4​],[NiCl4​]2−[Fe(CN)6​]4−,[Cu(NH3​)4​]2+[Fe(CN)6​]3−and[Fe(H2​O)6​]2+…2023 · Numerical
  • Match List I with List II Choose the correct answer from the options given below : Includes table2023 · MCQ
  • Total number of moles of AgCl precipitated on addition of excess of AgNO 3​ to one mole each of the following complexes [Co(NH3​)4​Cl2​]Cl,[Ni(H2​O)6​]Cl2​,[Pt(NH3​)2​Cl2​] and [Pd(NH3​)4​]Cl2​ is ​…2023 · Numerical
  • Chiral complex from the following is : Here en = ethylene diamine2023 · MCQ
  • The sum of bridging carbonyls in W(CO)6​ and Mn2​(CO)10​ is ​.2023 · Numerical
  • Correct order of spin only magnetic moment of the following complex ions is : (Given At.no. Fe : 26, Co : 27)2023 · MCQ