JEE MainChemistryCoordination CompoundsNumerical+4 / −1
The d-electronic configuration of in tetrahedral crystal field in . Sum of "m" and "number of unpaired electrons" is
Numerical answer
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Correct answer: 7
- Find oxidation state of Co in
Let oxidation state of Co be .
So, cobalt is .
- Write the d-electron count of
Atomic number of Co is .
Neutral Co:
For , remove two electrons from first:
So the ion has 7 d-electrons.
- Tetrahedral crystal field splitting
In a tetrahedral field, the lower energy set is and the higher energy set is .
Thus, electrons fill as:
Since tetrahedral complexes are generally high spin (because is small), for the arrangement is:
- First fill lower set: electrons maximum
- Then fill higher set with remaining electrons
So,
Hence,
- Find number of unpaired electrons
For tetrahedral :
- In , both orbitals are fully paired unpaired there
- In , the three electrons occupy three orbitals singly unpaired electrons
Therefore, number of unpaired electrons .
- Required sum
Final Answer
The derived answer matches the stored correct answer.
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