JEE MainChemistryCoordination CompoundsMCQ+4 / −1
The molecule in which hybrid MOs involve only one d-orbital of the central atom is :
- A
- B[Ni(CN)4]2–
- C[CrF6]3–
- D
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Correct answer: B
-
We need the species whose hybrid orbitals use only one -orbital of the central atom.
Let us examine the hybridization of the central atom in each option.
-
Option A:
- Shape: square planar
- Hybridization traditionally assigned:
- This involves two -orbitals.
So, does not satisfy the condition.
-
Option B:
- Oxidation state of Ni: \Rightarrow x = +2$$
- So Ni is with configuration:
- is a strong field ligand, so electrons pair up.
- For square planar complex, hybridization is:
- This uses one -orbital, one , and two orbitals.
Hence, this option does satisfy the condition.
-
Option C:
- Oxidation state of Cr: \Rightarrow x = +3$$
- So Cr is with configuration:
- is a weak field ligand.
- Octahedral complex formed with outer orbital hybridization:
- This uses two -orbitals.
So, this option does not satisfy the condition.
-
Option D:
- Shape: square pyramidal
- Hybridization traditionally assigned:
- This involves two -orbitals.
So, this option does not satisfy the condition.
-
Conclusion
Only has hybridization , involving exactly one -orbital of the central atom.
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