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Coordination Compounds question

2020 · 5 Sep · Shift 2 · Q8
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Coordination Compounds question

2020 · 5 Sep · Shift 2 · Q8

JEE MainChemistryCoordination CompoundsMCQ+4 / −1
Consider the complex ions, trans-[Co(en)2Cl2]+[Co(en)_2Cl_2]^+[Co(en)2​Cl2​]+ (A) and cis-[Co(en)2Cl2]+[Co(en)_2Cl_2]^+[Co(en)2​Cl2​]+ (B). The correct statement regarding them is :
  1. A
    both (A) and (B) can be optically active.
  2. B
    both (A) and (B) can not be optically active.
  3. C
    (A) can not be optically active, but (B) can be optically active.
  4. D
    (A) can be optically active, but (B) can not be optically active.
View written solutionFree

Correct answer: C

  1. Identify the geometry and ligands

The complexes are: trans-[Co(en)2Cl2]+(A),cis-[Co(en)2Cl2]+(B)\text{trans-}[Co(en)_2Cl_2]^+ \quad (A), \qquad \text{cis-}[Co(en)_2Cl_2]^+ \quad (B)trans-[Co(en)2​Cl2​]+(A),cis-[Co(en)2​Cl2​]+(B)

Here, enenen = ethylenediamine, which is a bidentate ligand. Since there are two enenen ligands and two Cl−Cl^-Cl− ligands, the coordination number is 666, so the complex is octahedral.

  1. Criterion for optical activity

A complex is optically active if it is chiral, i.e. it does not possess a plane of symmetry, center of symmetry, or improper axis of rotation.

  1. Analyze the trans isomer (A)\text{(A)}(A)

For trans-[Co(en)2Cl2]+\text{trans-}[Co(en)_2Cl_2]^+trans-[Co(en)2​Cl2​]+ the two chloride ligands are opposite to each other.

This arrangement has sufficient symmetry (in particular, it possesses a symmetry element making it superimposable on its mirror image), so the trans isomer is achiral.

Hence, (A) is not optically active.

  1. Analyze the cis isomer (B)\text{(B)}(B)

For cis-[Co(en)2Cl2]+\text{cis-}[Co(en)_2Cl_2]^+cis-[Co(en)2​Cl2​]+ the two chloride ligands are adjacent.

With two bidentate enenen ligands arranged in the cis form, the complex can adopt a helical arrangement, giving rise to non-superimposable mirror images (Δ\DeltaΔ and Λ\LambdaΛ forms).

Therefore, the cis isomer is chiral and can be optically active.

  1. Evaluate the options
  • A: both (A) and (B) can be optically active.
    False.
  • B: both (A) and (B) can not be optically active.
    False.
  • C: (A) can not be optically active, but (B) can be optically active.
    True.
  • D: (A) can be optically active, but (B) can not be optically active.
    False.

Therefore, the correct option is: C\boxed{\text{C}}C​

  1. Comparison with stored answer

Stored correct answer = C. This matches the derived answer.

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