- Aboth (A) and (B) can be optically active.
- Bboth (A) and (B) can not be optically active.
- C(A) can not be optically active, but (B) can be optically active.
- D(A) can be optically active, but (B) can not be optically active.
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Correct answer: C
- Identify the geometry and ligands
The complexes are:
Here, = ethylenediamine, which is a bidentate ligand. Since there are two ligands and two ligands, the coordination number is , so the complex is octahedral.
- Criterion for optical activity
A complex is optically active if it is chiral, i.e. it does not possess a plane of symmetry, center of symmetry, or improper axis of rotation.
- Analyze the trans isomer
For the two chloride ligands are opposite to each other.
This arrangement has sufficient symmetry (in particular, it possesses a symmetry element making it superimposable on its mirror image), so the trans isomer is achiral.
Hence, (A) is not optically active.
- Analyze the cis isomer
For the two chloride ligands are adjacent.
With two bidentate ligands arranged in the cis form, the complex can adopt a helical arrangement, giving rise to non-superimposable mirror images ( and forms).
Therefore, the cis isomer is chiral and can be optically active.
- Evaluate the options
- A: both (A) and (B) can be optically active.
False. - B: both (A) and (B) can not be optically active.
False. - C: (A) can not be optically active, but (B) can be optically active.
True. - D: (A) can be optically active, but (B) can not be optically active.
False.
Therefore, the correct option is:
- Comparison with stored answer
Stored correct answer = C. This matches the derived answer.
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