JEE MainChemistryCoordination CompoundsMCQ+4 / −1
For a d4 metal ion in an octahedral field, the correct electronic configuration is :
- Awhen 0 < P
- Bwhen 0 > P
- Cwhen 0 < P
- Dwhen 0 < P
View written solutionFree
Correct answer: D
-
For an octahedral field, the five -orbitals split into:
-
For a metal ion, we need to place 4 electrons in these orbitals. The arrangement depends on the comparison between:
- = octahedral crystal field splitting energy
- = pairing energy
-
Case 1:
- It is energetically cheaper to put the 4th electron into the higher orbital rather than pair up in .
- So the configuration is:
- This is the high-spin case.
-
Case 2:
- It is energetically cheaper to pair electrons in the lower set.
- So the configuration is:
- This is the low-spin case.
-
Now evaluate the options:
-
A: when
Wrong, because occurs when . -
B: when
Wrong, because occurs when . -
C: when
Wrong, electrons fill lower-energy first, so this arrangement is not correct. -
D: when
Correct.
-
-
Therefore, the correct answer is:
More from Coordination Compounds
- The IUPAC name of complex is:2020 · MCQ
- The theory that can completely/properly explain the nature of bonding in is :2020 · MCQ
- The number of possible optical isomers for the complexes MA2B2 with sp3 and dsp2 hydridized metal atom. respectively, is : Note : A and B are unidentate netural and unidentate monoanionic ligands, respectively.2020 · MCQ
- Among the statements(a)-(d) the incorrect ones are : (a) Octahedral CO(III) complexes with strong fields ligands have very high magnetic moments. (b) When 0 < P, the d-electron configuration of Co(III) in an octahedral complex…2020 · MCQ
- The complex that can show fac- and mer-isomers is :2020 · MCQ
- The correct order of the calculated spin-only magnetic moments of complexs (A) to (D) is: (A) (B) (C) (D) 2020 · MCQ
- Among (a) – (d) the complexes that can display geometrical isomerism are : (a) (b) (c) (d) 2020 · MCQ
- Complexes () of metals Ni and Fe have ideal square pyramidal and trigonal bipyramidal grometries, respectively. The sum of the 90°, 120° and 180° L-M-L angles in the two complexes is .2020 · Numerical