Sign in
12thPass logo
New chatPYQ LibraryDoubtsRank report
Sign in to see Recents

Your guest activity stays on this device

Sign in to save progress →
Sign in

Coordination Compounds question

2020 · 6 Sep · Shift 2 · Q11
Guest · filters and generic practice availableBrowsing as a guest · PYQ filters and generic practice are available. Sign in only for personalised features and saved progress.
  1. PYQ Library
  2. /JEE Main
  3. /Chemistry
  4. /Coordination Compounds
  5. /2020 · 6 Sep · Shift 2 · Q11

Coordination Compounds question

2020 · 6 Sep · Shift 2 · Q11

JEE MainChemistryCoordination CompoundsMCQ+4 / −1
For a d4 metal ion in an octahedral field, the correct electronic configuration is :
  1. A
    t2g4eg0t_{2g}^4e_g^0t2g4​eg0​ when Δ\DeltaΔ 0 < P
  2. B
    t2g3eg1t_{2g}^3e_g^1t2g3​eg1​ when Δ\DeltaΔ 0 > P
  3. C
    eg2t2g2e_g^2t_{2g}^2eg2​t2g2​ when Δ\DeltaΔ 0 < P
  4. D
    t2g3eg1t_{2g}^3e_g^1t2g3​eg1​ when Δ\DeltaΔ 0 < P
View written solutionFree

Correct answer: D

  1. For an octahedral field, the five ddd-orbitals split into: t2g (lower energy)andeg (higher energy)t_{2g} \text{ (lower energy)} \quad \text{and} \quad e_g \text{ (higher energy)}t2g​ (lower energy)andeg​ (higher energy)

  2. For a d4d^4d4 metal ion, we need to place 4 electrons in these orbitals. The arrangement depends on the comparison between:

    • Δo\Delta_oΔo​ = octahedral crystal field splitting energy
    • PPP = pairing energy
  3. Case 1: Δo<P\Delta_o < PΔo​<P

    • It is energetically cheaper to put the 4th electron into the higher ege_geg​ orbital rather than pair up in t2gt_{2g}t2g​.
    • So the configuration is: t2g3eg1t_{2g}^3 e_g^1t2g3​eg1​
    • This is the high-spin case.
  4. Case 2: Δo>P\Delta_o > PΔo​>P

    • It is energetically cheaper to pair electrons in the lower t2gt_{2g}t2g​ set.
    • So the configuration is: t2g4eg0t_{2g}^4 e_g^0t2g4​eg0​
    • This is the low-spin case.
  5. Now evaluate the options:

    • A: t2g4eg0t_{2g}^4e_g^0t2g4​eg0​ when Δo<P\Delta_o < PΔo​<P
      Wrong, because t2g4eg0t_{2g}^4e_g^0t2g4​eg0​ occurs when Δo>P\Delta_o > PΔo​>P.

    • B: t2g3eg1t_{2g}^3e_g^1t2g3​eg1​ when Δo>P\Delta_o > PΔo​>P
      Wrong, because t2g3eg1t_{2g}^3e_g^1t2g3​eg1​ occurs when Δo<P\Delta_o < PΔo​<P.

    • C: eg2t2g2e_g^2t_{2g}^2eg2​t2g2​ when Δo<P\Delta_o < PΔo​<P
      Wrong, electrons fill lower-energy t2gt_{2g}t2g​ first, so this arrangement is not correct.

    • D: t2g3eg1t_{2g}^3e_g^1t2g3​eg1​ when Δo<P\Delta_o < PΔo​<P
      Correct.

  6. Therefore, the correct answer is: D\boxed{D}D​

PreviousNext

More from Coordination Compounds

  • The IUPAC name of complex [Pt(NH3​)2​Cl(NH2​CH3​)]Cl is:2020 · MCQ
  • The theory that can completely/properly explain the nature of bonding in [Ni(Co)4​] is :2020 · MCQ
  • The number of possible optical isomers for the complexes MA2B2 with sp3 and dsp2 hydridized metal atom. respectively, is : Note : A and B are unidentate netural and unidentate monoanionic ligands, respectively.2020 · MCQ
  • Among the statements(a)-(d) the incorrect ones are : (a) Octahedral CO(III) complexes with strong fields ligands have very high magnetic moments. (b) When Δ 0 < P, the d-electron configuration of Co(III) in an octahedral complex…2020 · MCQ
  • The complex that can show fac- and mer-isomers is :2020 · MCQ
  • The correct order of the calculated spin-only magnetic moments of complexs (A) to (D) is: (A) Ni(CO)4​ (B) [Ni(H2​O)6​]Cl2​ (C) Na2​[Ni(CN)4​] (D) PdCl2​(PPh3​)2​2020 · MCQ
  • Among (a) – (d) the complexes that can display geometrical isomerism are : (a) [Pt(NH3​)3​Cl]+ (b) [Pt(NH3​)Cl5​]– (c) [Pt(NH3​)2​Cl(NO2​)] (d) [Pt(NH3​)4​ClBr]2+2020 · MCQ
  • Complexes (ML5​) of metals Ni and Fe have ideal square pyramidal and trigonal bipyramidal grometries, respectively. The sum of the 90°, 120° and 180° L-M-L angles in the two complexes is ​.2020 · Numerical