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Compounds Containing Nitrogen question

2024 · 5 Apr · Shift 2 · Q29
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  5. /2024 · 5 Apr · Shift 2 · Q29

Compounds Containing Nitrogen question

2024 · 5 Apr · Shift 2 · Q29

JEE MainChemistryCompounds Containing NitrogenNumerical+4 / −1
X g\mathrm{X} \mathrm{~g}X g of ethanamine was subjected to reaction with NaNO2/HCl\mathrm{NaNO}_2 / \mathrm{HCl}NaNO2​/HCl followed by hydrolysis to liberate N2\mathrm{N}_2N2​ and HCl\mathrm{HCl}HCl. The HCl\mathrm{HCl}HCl generated was completely neutralised by 0.2 moles of NaOH.X\mathrm{NaOH} . \mathrm{X}NaOH.X is ‾\underline{\hspace{2cm}}​ g.
Numerical answer
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Correct answer: 9

  1. Write the reaction of ethanamine with nitrous acid

Ethanamine is a primary aliphatic amine: C2H5NH2\mathrm{C_2H_5NH_2}C2​H5​NH2​

With NaNO2/HCl\mathrm{NaNO_2/HCl}NaNO2​/HCl, nitrous acid (HNO2\mathrm{HNO_2}HNO2​) is generated in situ, and primary aliphatic amines react as: RNH2+HNO2→ROH+N2+H2O\mathrm{RNH_2 + HNO_2 \rightarrow ROH + N_2 + H_2O}RNH2​+HNO2​→ROH+N2​+H2​O

For ethanamine: C2H5NH2+HNO2→C2H5OH+N2+H2O\mathrm{C_2H_5NH_2 + HNO_2 \rightarrow C_2H_5OH + N_2 + H_2O}C2​H5​NH2​+HNO2​→C2​H5​OH+N2​+H2​O

  1. Account for HCl consumed and regenerated

NaNO2/HCl\mathrm{NaNO_2/HCl}NaNO2​/HCl means HCl\mathrm{HCl}HCl is used to generate nitrous acid: NaNO2+HCl→HNO2+NaCl\mathrm{NaNO_2 + HCl \rightarrow HNO_2 + NaCl}NaNO2​+HCl→HNO2​+NaCl

Thus, for each mole of ethanamine reacting, 1 mole of HCl is consumed to form HNO2\mathrm{HNO_2}HNO2​.

Now, the question says that after reaction and hydrolysis, N2\mathrm{N_2}N2​ and HCl\mathrm{HCl}HCl are liberated. This corresponds to the standard diazotization representation in acid medium: C2H5NH2+NaNO2+HCl→C2H5OH+N2+NaCl+H2O\mathrm{C_2H_5NH_2 + NaNO_2 + HCl \rightarrow C_2H_5OH + N_2 + NaCl + H_2O}C2​H5​NH2​+NaNO2​+HCl→C2​H5​OH+N2​+NaCl+H2​O

The problem directly states that the HCl generated was completely neutralised by 0.20.20.2 mol of NaOH\mathrm{NaOH}NaOH.

Neutralisation is: HCl+NaOH→NaCl+H2O\mathrm{HCl + NaOH \rightarrow NaCl + H_2O}HCl+NaOH→NaCl+H2​O

So, moles of HCl=moles of NaOH=0.2\text{moles of HCl} = \text{moles of NaOH} = 0.2moles of HCl=moles of NaOH=0.2

  1. Relate moles of HCl to moles of ethanamine

From the reaction stoichiometry, 1 mole of ethanamine corresponds to 1 mole of HCl involved/generated as indicated by the problem statement.

Hence, moles of ethanamine: n=0.2 moln = 0.2 \text{ mol}n=0.2 mol

  1. Calculate mass of ethanamine

Molar mass of ethanamine, C2H7N\mathrm{C_2H_7N}C2​H7​N: 2×12+7×1+14=24+7+14=45 g mol−12\times 12 + 7\times 1 + 14 = 24 + 7 + 14 = 45\,\text{g mol}^{-1}2×12+7×1+14=24+7+14=45g mol−1

Therefore, X=nM=0.2×45=9 gX = nM = 0.2 \times 45 = 9\,\text{g}X=nM=0.2×45=9g

  1. Final answer

9\boxed{9}9​

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