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Correct answer: 9
- Write the reaction of ethanamine with nitrous acid
Ethanamine is a primary aliphatic amine:
With , nitrous acid () is generated in situ, and primary aliphatic amines react as:
For ethanamine:
- Account for HCl consumed and regenerated
means is used to generate nitrous acid:
Thus, for each mole of ethanamine reacting, 1 mole of HCl is consumed to form .
Now, the question says that after reaction and hydrolysis, and are liberated. This corresponds to the standard diazotization representation in acid medium:
The problem directly states that the HCl generated was completely neutralised by mol of .
Neutralisation is:
So,
- Relate moles of HCl to moles of ethanamine
From the reaction stoichiometry, 1 mole of ethanamine corresponds to 1 mole of HCl involved/generated as indicated by the problem statement.
Hence, moles of ethanamine:
- Calculate mass of ethanamine
Molar mass of ethanamine, :
Therefore,
- Final answer
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