JEE MainChemistryCompounds Containing NitrogenNumerical+4 / −1
of pure aniline upon diazotisation followed by coupling with phenol gives an orange dye. The mass of orange dye produced (assume 100% yield/conversion) is g. (nearest integer)
Numerical answer
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Correct answer: 20
- Identify the reaction sequence
Aniline undergoes diazotisation to form benzenediazonium chloride, which then couples with phenol to give an azo dye:
Then,
The orange dye formed is p-hydroxyazobenzene.
- Find moles of aniline
Molar mass of aniline, :
Given mass of aniline =
- Use stoichiometry
Diazotisation is a conversion, and azo coupling with phenol also gives formation of dye.
So,
- Find molar mass of the dye
The dye is -hydroxyazobenzene with formula:
Molar mass:
- Calculate mass of dye formed
Nearest integer:
- Compare with stored answer
Stored correct answer =
Our derived answer =
So they agree.
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