JEE MainChemistryChemical Kinetics and Nuclear ChemistryMCQ+4 / −1
A person's wound was exposed to some bacteria and then bacterial growth started to happen at the same place. The wound was later treated with some antibacterial medicine and the rate of bacterial decay(r) was found to be proportional with the square of the existing number of bacteria at any instance. Which of the following set of graphs correctly represents the 'before' and 'after' situation of the application of the medicine? [Given: No. of bacteria, time, bacterial growth follows order kinetics.]
- A

- B

- C

- D

View written solutionFree
Correct answer: C
-
Before applying the medicine: bacterial growth
It is given that bacterial growth follows first-order kinetics.
For first-order growth, where is the number of bacteria.
Integrating,
So, before medicine is applied:
- increases exponentially with time.
- Hence the vs graph should be an increasing, concave upward curve.
-
After applying the medicine: bacterial decay
It is given that the rate of bacterial decay is proportional to the square of the existing number of bacteria.
Therefore, or
Rearranging,
Integrating,
If at , , then
Thus,
So after medicine is applied:
- decreases with time.
- The decay is not exponential.
- The vs graph is a decreasing hyperbola-like curve, falling rapidly at first and then flattening out.
-
What kind of graphs are expected?
Therefore, the correct set must show:
- Before treatment: exponential increase in vs
- After treatment: second-order decay, i.e. a decreasing curve of the form
-
Matching with options
Among the given options, the graph set that corresponds to:
- first-order bacterial growth before medicine, and
- second-order decay after medicine
is Option C.
-
Final answer
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