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Chemical Kinetics and Nuclear Chemistry question

2025 · 7 Apr · Shift 1 · Q2
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Chemical Kinetics and Nuclear Chemistry question

2025 · 7 Apr · Shift 1 · Q2

JEE MainChemistryChemical Kinetics and Nuclear ChemistryMCQ+4 / −1
A person's wound was exposed to some bacteria and then bacterial growth started to happen at the same place. The wound was later treated with some antibacterial medicine and the rate of bacterial decay(r) was found to be proportional with the square of the existing number of bacteria at any instance. Which of the following set of graphs correctly represents the 'before' and 'after' situation of the application of the medicine? [Given: N=N=N= No. of bacteria, t=t=t= time, bacterial growth follows 1st 1^{\text {st }}1st  order kinetics.]
  1. A
    JEE Main 2025 (Online) 7th April Morning Shift Chemistry - Chemical Kinetics and Nuclear Chemistry Question 9 English Option 1
  2. B
    JEE Main 2025 (Online) 7th April Morning Shift Chemistry - Chemical Kinetics and Nuclear Chemistry Question 9 English Option 2
  3. C
    JEE Main 2025 (Online) 7th April Morning Shift Chemistry - Chemical Kinetics and Nuclear Chemistry Question 9 English Option 3
  4. D
    JEE Main 2025 (Online) 7th April Morning Shift Chemistry - Chemical Kinetics and Nuclear Chemistry Question 9 English Option 4
View written solutionFree

Correct answer: C

  1. Before applying the medicine: bacterial growth

    It is given that bacterial growth follows first-order kinetics.

    For first-order growth, dNdt=kN\frac{dN}{dt}=kNdtdN​=kN where NNN is the number of bacteria.

    Integrating, N=N0ektN=N_0 e^{kt}N=N0​ekt

    So, before medicine is applied:

    • NNN increases exponentially with time.
    • Hence the NNN vs ttt graph should be an increasing, concave upward curve.
  2. After applying the medicine: bacterial decay

    It is given that the rate of bacterial decay is proportional to the square of the existing number of bacteria.

    Therefore, −dNdt=kN2-\frac{dN}{dt}=kN^2−dtdN​=kN2 or dNdt=−kN2\frac{dN}{dt}=-kN^2dtdN​=−kN2

    Rearranging, dNN2=−k dt\frac{dN}{N^2}=-k\,dtN2dN​=−kdt

    Integrating, −1N=−kt+C-\frac{1}{N}=-kt+C−N1​=−kt+C 1N=kt+C′\frac{1}{N}=kt+C'N1​=kt+C′

    If at t=0t=0t=0, N=N0N=N_0N=N0​, then 1N=kt+1N0\frac{1}{N}=kt+\frac{1}{N_0}N1​=kt+N0​1​

    Thus, N=1kt+1N0=N01+kN0tN=\frac{1}{kt+\frac{1}{N_0}}=\frac{N_0}{1+kN_0 t}N=kt+N0​1​1​=1+kN0​tN0​​

    So after medicine is applied:

    • NNN decreases with time.
    • The decay is not exponential.
    • The NNN vs ttt graph is a decreasing hyperbola-like curve, falling rapidly at first and then flattening out.
  3. What kind of graphs are expected?

    Therefore, the correct set must show:

    • Before treatment: exponential increase in NNN vs ttt
    • After treatment: second-order decay, i.e. a decreasing curve of the form N=N01+kN0tN=\frac{N_0}{1+kN_0 t}N=1+kN0​tN0​​
  4. Matching with options

    Among the given options, the graph set that corresponds to:

    • first-order bacterial growth before medicine, and
    • second-order decay after medicine

    is Option C.

  5. Final answer

    C\boxed{\text{C}}C​

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