Sign in
12thPass logo
New chatPYQ LibraryDoubtsRank report
Sign in to see Recents

Your guest activity stays on this device

Sign in to save progress →
Sign in

Chemical Equilibrium question

2024 · 29 Jan · Shift 1 · Q24
Guest · filters and generic practice availableBrowsing as a guest · PYQ filters and generic practice are available. Sign in only for personalised features and saved progress.
  1. PYQ Library
  2. /JEE Main
  3. /Chemistry
  4. /Chemical Equilibrium
  5. /2024 · 29 Jan · Shift 1 · Q24

Chemical Equilibrium question

2024 · 29 Jan · Shift 1 · Q24

JEE MainChemistryChemical EquilibriumNumerical+4 / −1
For the reaction N2O4( g)⇄2NO2( g),Kp=0.492 atm\mathrm{N}_2 \mathrm{O}_{4(\mathrm{~g})} \rightleftarrows 2 \mathrm{NO}_{2(\mathrm{~g})}, \mathrm{K}_{\mathrm{p}}=0.492 \mathrm{~atm}N2​O4( g)​⇄2NO2( g)​,Kp​=0.492 atm at 300 K.Kc300 \mathrm{~K} . \mathrm{K}_{\mathrm{c}}300 K.Kc​ for the reaction at same temperature is ‾\underline{\hspace{2cm}}​×10−2\times 10^{-2}×10−2. (Given : R=0.082 L atm mol−1 K−1\mathrm{R}=0.082 \mathrm{~L} \mathrm{~atm} \mathrm{~mol}^{-1} \mathrm{~K}^{-1}R=0.082 L atm mol−1 K−1)
Numerical answer
View written solutionFree

Correct answer: 2

  1. For the reaction N2O4(g)⇌2 NO2(g)\mathrm{N_2O_4(g)} \rightleftharpoons 2\,\mathrm{NO_2(g)}N2​O4​(g)⇌2NO2​(g) the relation between KpK_pKp​ and KcK_cKc​ is Kp=Kc(RT)ΔnK_p = K_c (RT)^{\Delta n}Kp​=Kc​(RT)Δn where Δn=(moles of gaseous products)−(moles of gaseous reactants)=2−1=1.\Delta n = (\text{moles of gaseous products}) - (\text{moles of gaseous reactants}) = 2 - 1 = 1.Δn=(moles of gaseous products)−(moles of gaseous reactants)=2−1=1.

  2. Hence, Kp=Kc(RT)K_p = K_c (RT)Kp​=Kc​(RT) so Kc=KpRT.K_c = \frac{K_p}{RT}.Kc​=RTKp​​.

  3. Substitute the given values: Kp=0.492,R=0.082 L atm mol−1 K−1,T=300 KK_p = 0.492, \quad R = 0.082\,\mathrm{L\,atm\,mol^{-1}\,K^{-1}}, \quad T=300\,\mathrm{K}Kp​=0.492,R=0.082Latmmol−1K−1,T=300K

    Kc=0.4920.082×300K_c = \frac{0.492}{0.082 \times 300}Kc​=0.082×3000.492​

  4. Calculate denominator: 0.082×300=24.60.082 \times 300 = 24.60.082×300=24.6

    Therefore, Kc=0.49224.6=0.02=2×10−2.K_c = \frac{0.492}{24.6} = 0.02 = 2 \times 10^{-2}.Kc​=24.60.492​=0.02=2×10−2.

  5. So the required integer in the blank is 2.\boxed{2}.2​.

PreviousNext

More from Chemical Equilibrium

  • The following concentrations were observed at 500 K for the formation of NH3​ from N2​ and H2​. At equilibrium ; [N2​]=2×10−2M,[H2​]=3×10−2M…2024 · Numerical
  • For the given reaction, choose the correct expression of KC​ from the following :-Fe(aq)3+​+SCN(aq)−​⇌(FeSCN)(aq)2+​2024 · MCQ
  • A(g)​⇌B(g)​+2C​(g) The correct relationship between KP​,α and equilibrium pressure P is2024 · MCQ
  • (i) X(g)⇌Y(g)+Z(g)Kp1​=3(ii) A(g)⇌2 B(g)Kp2​=1…2023 · Numerical
  • The effect of addition of helium gas to the following reaction in equilibrium state, is : PCl5​(g)⇌PCl3​(g)+Cl2​(g)2023 · Multiple correct
  • For a concentrated solution of a weak electrolyte (Keq ​= equilibrium constant) A2​B3​ of concentration 'c', the degree of dissociation 'α' is :2023 · MCQ
  • The equilibrium composition for the reaction PCl3​+Cl2​⇌PCl5​ at 298 K is given below: [PCl3​]eq​=0.2 mol L−1,[Cl2​]eq​=0.1 mol L−1,[PCl5​]eq​=0.40 mol L−1…2023 · Numerical
  • The number of correct statement/s involving equilibria in physical processes from the following is ​ (A) Equilibrium is possible only in a closed system at a given temperature. (B) Both the opposing processes occur…2023 · Numerical