JEE MainChemistryChemical EquilibriumNumerical+4 / −1
2(g) 3(g) At 300 K, ozone is fifty percent dissociated. The standard free energy change at this temperature and 1 atm pressure is () J mol 1. (Nearest integer) [Given : ln 1.35 = 0.3 and R = 8.3 J K 1 mol 1]
Numerical answer
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Correct answer: 747
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Reaction and given data
The reaction is
At , ozone is dissociated.
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Assume initial moles
Let initial moles of and initially no .
Since dissociation is , moles of dissociated .
From
if mol of is consumed, then moles of formed are
So at equilibrium:
- Total moles
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Equilibrium partial pressures at total pressure
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Equilibrium constant in terms of pressure
Substituting:
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Relation between standard free energy and equilibrium constant
Given:
Therefore,
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Final integer asked
Since the question is of the form "The standard free energy change is ", the blank should be filled by
Comparison with stored answer: Stored correct answer is , which matches the derived answer.
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