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Chemical Equilibrium question

2022 · 24 Jun · Shift 1 · Q13
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Chemical Equilibrium question

2022 · 24 Jun · Shift 1 · Q13

JEE MainChemistryChemical EquilibriumNumerical+4 / −1
2O3O_3O3​(g) ⇌\rightleftharpoons⇌ 3O2O_2O2​(g) At 300 K, ozone is fifty percent dissociated. The standard free energy change at this temperature and 1 atm pressure is (−-−) ‾\underline{\hspace{2cm}}​ J mol −-− 1. (Nearest integer) [Given : ln 1.35 = 0.3 and R = 8.3 J K −-− 1 mol −-− 1]
Numerical answer
View written solutionFree

Correct answer: 747

  1. Reaction and given data

    The reaction is 2O3(g)⇌3O2(g)2O_3(g) \rightleftharpoons 3O_2(g)2O3​(g)⇌3O2​(g)

    At 300 K300\,\text{K}300K, ozone is 50%50\%50% dissociated.

  2. Assume initial moles

    Let initial moles of O3=1O_3 = 1O3​=1 and initially no O2O_2O2​.

    Since dissociation is 50%50\%50%, moles of O3O_3O3​ dissociated =0.5=0.5=0.5.

    From 2O3→3O22O_3 \rightarrow 3O_22O3​→3O2​

    if 0.50.50.5 mol of O3O_3O3​ is consumed, then moles of O2O_2O2​ formed are 0.5×32=0.750.5\times \frac{3}{2}=0.750.5×23​=0.75

    So at equilibrium:

    • O3=1−0.5=0.5O_3 = 1-0.5=0.5O3​=1−0.5=0.5
    • O2=0.75O_2 = 0.75O2​=0.75
    • Total moles =0.5+0.75=1.25=0.5+0.75=1.25=0.5+0.75=1.25
  3. Equilibrium partial pressures at total pressure 1 atm1\,\text{atm}1atm

    pO3=0.51.25=0.4 atmp_{O_3}=\frac{0.5}{1.25}=0.4\,\text{atm}pO3​​=1.250.5​=0.4atm pO2=0.751.25=0.6 atmp_{O_2}=\frac{0.75}{1.25}=0.6\,\text{atm}pO2​​=1.250.75​=0.6atm

  4. Equilibrium constant in terms of pressure

    Kp=(pO2)3(pO3)2K_p=\frac{(p_{O_2})^3}{(p_{O_3})^2}Kp​=(pO3​​)2(pO2​​)3​

    Substituting: Kp=(0.6)3(0.4)2K_p=\frac{(0.6)^3}{(0.4)^2}Kp​=(0.4)2(0.6)3​ Kp=0.2160.16=1.35K_p=\frac{0.216}{0.16}=1.35Kp​=0.160.216​=1.35

  5. Relation between standard free energy and equilibrium constant

    ΔG∘=−RTln⁡Kp\Delta G^\circ=-RT\ln K_pΔG∘=−RTlnKp​

    Given: R=8.3 J K−1mol−1,T=300 K,ln⁡1.35=0.3R=8.3\,\text{J K}^{-1}\text{mol}^{-1},\quad T=300\,\text{K},\quad \ln 1.35=0.3R=8.3J K−1mol−1,T=300K,ln1.35=0.3

    Therefore, ΔG∘=−(8.3)(300)(0.3)\Delta G^\circ=-(8.3)(300)(0.3)ΔG∘=−(8.3)(300)(0.3) ΔG∘=−747 J mol−1\Delta G^\circ=-747\,\text{J mol}^{-1}ΔG∘=−747J mol−1

  6. Final integer asked

    Since the question is of the form "The standard free energy change is (−) ‾ J mol−1(-)\,\underline{\hspace{1cm}}\,\text{J mol}^{-1}(−)​J mol−1", the blank should be filled by 747747747

Comparison with stored answer: Stored correct answer is 747747747, which matches the derived answer.

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