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Correct answer: 5470
- Write the decomposition reaction
We are told that at equilibrium, 40% of HI decomposes at .
- Take initial moles and find equilibrium moles
Assume initially:
If of decomposes, then moles of consumed are:
From
if mol of is consumed, then extent gives:
So equilibrium moles are:
Total moles at equilibrium:
Hence mole fractions are the same as the moles:
Since total pressure is ,
- Find equilibrium constant
For the reaction
Substitute values:
Because , we have:
So,
- Use relation between standard Gibbs free energy and equilibrium constant
Thus,
Since
so
Now,
Given:
Therefore,
Hence,
Now calculate:
Nearest integer:
- Comparison with stored correct answer
Stored answer =
My derived answer =
The stored answer appears to be exactly half of the correct value, which may arise if one incorrectly writes the reaction as
and then uses the equilibrium constant expression inconsistently with the given decomposition percentage. But the standard decomposition reaction is
for which the correct value is
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