JEE MainChemistryChemical EquilibriumNumerical+4 / −1
At of are mixed with of . The reaction occurring as above comes to equilibrium under a total pressure of 1 atm. Analysis of the system shows that of oxygen are present at equilibrium. The equilibrium constant for the reaction is . (Nearest integer)
Numerical answer
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Correct answer: 2
- Given reaction
We need to find the equilibrium constant at .
- Initial moles
At equilibrium, oxygen present is mol.
So oxygen consumed is
- Use stoichiometry
From the reaction,
Therefore, if mol is consumed:
Thus equilibrium moles are:
- Total moles at equilibrium
Total pressure is atm, so partial pressures are mole fractions times total pressure.
- Expression for equilibrium constant
For the reaction,
Substitute values:
Simplify:
Since
So
- Nearest integer
- Comparison with stored answer
Stored correct answer = .
Our derived answer matches it.
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