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Chemical Bonding and Molecular Structure question

2018 · Shift 0 · Q24
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Chemical Bonding and Molecular Structure question

2018 · Shift 0 · Q24

JEE MainChemistryChemical Bonding and Molecular StructureMCQ+4 / −1
Total number of lone pair of electrons in I3−{\rm I}_3^ -I3−​ ion is
  1. A
    3
  2. B
    9
  3. C
    6
  4. D
    12
View written solutionFree

Correct answer: B

  1. Count total valence electrons in I3−{\rm I}_3^-I3−​:

    • Each iodine atom has 777 valence electrons.
    • For 333 iodine atoms: 3×7=213 \times 7 = 213×7=21
    • One extra electron due to the negative charge: 21+1=2221 + 1 = 2221+1=22

    So, total valence electrons =22= 22=22.

  2. Draw the basic structure:

    The ion is linear with one central iodine: I−I−I\mathrm{I-I-I}I−I−I

    There are two single bonds.

  3. Count electrons used in bonding:

    • Each single bond contains 222 electrons.
    • Two bonds use 2×2=42 \times 2 = 42×2=4 electrons.

    Remaining electrons: 22−4=1822 - 4 = 1822−4=18

  4. Convert remaining electrons into lone pairs:

    • Each lone pair contains 222 electrons.
    • Therefore, number of lone pairs: 182=9\frac{18}{2} = 9218​=9
  5. Check distribution:

    • Each terminal iodine has 333 lone pairs.
    • Central iodine also has 333 lone pairs.

    Total lone pairs: 3+3+3=93 + 3 + 3 = 93+3+3=9

  6. Evaluate options:

    • A: 333 ❌
    • B: 999 ✅
    • C: 666 ❌
    • D: 121212 ❌

Therefore, the total number of lone pairs in I3−{\rm I}_3^-I3−​ is 9.

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