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Chemical Bonding and Molecular Structure question

2016 · Shift 0 · Q19
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Chemical Bonding and Molecular Structure question

2016 · Shift 0 · Q19

JEE MainChemistryChemical Bonding and Molecular StructureMCQ+4 / −1
The species in which the N\mathrm{N}N atom is in a state of sps psp hybridization is :
  1. A
    NO2+\mathrm{NO}_2^{+}NO2+​
  2. B
    NO2−\mathrm{NO}_2^{-}NO2−​
  3. C
    NO3−\mathrm{NO}_3^{-}NO3−​
  4. D
    NO3−\mathrm{NO}_3^{-}NO3−​
View written solutionFree

Correct answer: A

  1. Determine the hybridization of nitrogen in each species using steric number:

    Steric number=number of σ-bonds+number of lone pairs on central atom\text{Steric number} = \text{number of } \sigma\text{-bonds} + \text{number of lone pairs on central atom}Steric number=number of σ-bonds+number of lone pairs on central atom

  2. Option A: NO2+\mathrm{NO_2^+}NO2+​ (nitronium ion)

    Structure: O=N=O\mathrm{O=N=O}O=N=O Nitrogen is the central atom.

    • Number of σ\sigmaσ-bonds on N = 2
    • Number of lone pairs on N = 0

    So, Steric number=2+0=2\text{Steric number} = 2 + 0 = 2Steric number=2+0=2 Hybridization for steric number 2 is: spspsp

  3. Option B: NO2−\mathrm{NO_2^-}NO2−​ (nitrite ion)

    Resonance structure has N central with two O atoms and one lone pair on N.

    • Number of σ\sigmaσ-bonds on N = 2
    • Number of lone pairs on N = 1

    So, Steric number=2+1=3\text{Steric number} = 2 + 1 = 3Steric number=2+1=3 Therefore, hybridization is: sp2sp^2sp2

  4. Option C: NO3−\mathrm{NO_3^-}NO3−​ (nitrate ion)

    Nitrogen is bonded to three oxygen atoms, with no lone pair on N.

    • Number of σ\sigmaσ-bonds on N = 3
    • Number of lone pairs on N = 0

    So, Steric number=3+0=3\text{Steric number} = 3 + 0 = 3Steric number=3+0=3 Therefore, hybridization is: sp2sp^2sp2

  5. Option D: NO3−\mathrm{NO_3^-}NO3−​

    This is identical to option C, so again the hybridization is: sp2sp^2sp2

  6. Conclusion The species in which nitrogen is spspsp hybridized is: NO2+\boxed{\mathrm{NO_2^+}}NO2+​​

  7. Comparison with stored answer Stored correct answer: A

    Our derived answer is also A, so they agree.

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