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Chemical Bonding and Molecular Structure question

2004 · Shift 0 · Q64
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Chemical Bonding and Molecular Structure question

2004 · Shift 0 · Q64

JEE MainChemistryChemical Bonding and Molecular StructureMCQ+4 / −1
The states of hybridization of boron and oxygen atoms in boric acid (H3BO3H_3BO_3H3​BO3​) are respectively
  1. A
    sp2 and sp2
  2. B
    sp3 and sp3
  3. C
    sp3 and sp2
  4. D
    sp2 and sp3
View written solutionFree

Correct answer: D

  1. Write the structure of boric acid

    Boric acid is better represented as B(OH)3B(OH)_3B(OH)3​ where boron is bonded to three hydroxyl groups.

  2. Hybridization of boron

    • Boron forms three σ\sigmaσ bonds with three oxygen atoms.
    • There is no lone pair on boron in H3BO3H_3BO_3H3​BO3​.
    • Hence, the steric number of boron is 333.

    Therefore, boron has trigonal planar geometry and is sp2\boxed{sp^2}sp2​ hybridized.

  3. Hybridization of oxygen

    Consider one oxygen atom in an −OH-OH−OH group:

    • It makes two σ\sigmaσ bonds: one with BBB and one with HHH.
    • It has two lone pairs.

    So, the steric number of oxygen is 2 bond pairs+2 lone pairs=42\text{ bond pairs} + 2\text{ lone pairs} = 42 bond pairs+2 lone pairs=4

    Hence oxygen is sp3\boxed{sp^3}sp3​ hybridized.

  4. Match with options

    • Boron: sp2sp^2sp2
    • Oxygen: sp3sp^3sp3

    So the correct option is D: sp2 and sp3\boxed{\text{D: } sp^2 \text{ and } sp^3}D: sp2 and sp3​

  5. Compare with stored correct answer

    Stored correct answer = D

    Our derived answer = D

    Therefore, they agree.

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