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Chemical Bonding and Molecular Structure question

2002 · Shift 0 · Q43
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Chemical Bonding and Molecular Structure question

2002 · Shift 0 · Q43

JEE MainChemistryChemical Bonding and Molecular StructureMCQ+4 / −1
Which of the following statements is true?
  1. A
    HF is less polar than HBr
  2. B
    absolutely pure water does not contain any ions
  3. C
    chemical bond formation takes place when forces of attraction overcome the forces of repulsion
  4. D
    in covalency transference of electron takes place
View written solutionFree

Correct answer: C

  1. Check option A: HF is less polar than HBr

    Polarity depends on electronegativity difference.

    • Electronegativity of FFF is much higher than that of HHH.
    • Electronegativity of BrBrBr is lower than that of FFF.

    Therefore, the bond in HFHFHF has a greater electronegativity difference than in HBrHBrHBr, so HFHFHF is more polar, not less polar.

    Hence, A is false.

  2. Check option B: absolutely pure water does not contain any ions

    Even absolutely pure water undergoes self-ionization: 2H2O⇌H3O++OH−2H_2O \rightleftharpoons H_3O^+ + OH^-2H2​O⇌H3​O++OH−

    So pure water contains a very small concentration of ions.

    Hence, B is false.

  3. Check option C: chemical bond formation takes place when forces of attraction overcome the forces of repulsion

    A chemical bond forms when the net attractive interactions between atoms lower the energy of the system.

    In bond formation:

    • nucleus-electron attractions act,
    • electron-electron and nucleus-nucleus repulsions also act,
    • bond forms only when attraction dominates sufficiently to give a lower-energy stable arrangement.

    Hence, C is true.

  4. Check option D: in covalency transference of electron takes place

    In a covalent bond, electrons are shared, not transferred.

    Electron transfer is characteristic of ionic bonding.

    Hence, D is false.

  5. Conclusion

    The only true statement is: C\boxed{\text{C}}C​

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