JEE MainChemistryBasics of Organic ChemistryMCQ+4 / −1
The correct IUPAC name of the following compound is : 

- A2-methyl-5-nitro-1-chlorobenzene
- B2-chloro-1-methyl-4-nitrobenzene
- C3-chloro-4-methyl-1-nitrobenzene
- D5-chloro-4-methyl-1-nitrobenzene
View written solutionFree
Correct answer: B
-
Interpret the substituted benzene ring
The compound has three substituents on benzene:
- one methyl group,
- one chloro group,
- one nitro group.
-
Apply IUPAC numbering rule
For a trisubstituted benzene, we must number the ring so that the substituents get the lowest set of locants.
From the given arrangement, if we assign:
- methyl as position 1,
- chloro as position 2,
- nitro as position 4,
then the locant set is:
This is lower than alternatives such as:
Hence the correct numbering is:
- 1-methyl
- 2-chloro
- 4-nitro
-
Write substituents in alphabetical order
Prefixes are written alphabetically:
- chloro
- methyl
- nitro
Therefore the name becomes:
-
Check options
- A: 2-methyl-5-nitro-1-chlorobenzene → numbering not lowest.
- B: 2-chloro-1-methyl-4-nitrobenzene → correct.
- C: 3-chloro-4-methyl-1-nitrobenzene → locants not lowest.
- D: 5-chloro-4-methyl-1-nitrobenzene → locants not lowest.
So, the correct option is B.
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