- ARf value depends on the type of chromatography.
- BHigher Rf value means higher adsorption.
- CRf value is dependent on the mobile phase.
- DThe value of Rf can not be more than one.
View written solutionFree
Correct answer: B
- Recall the definition of
In chromatography (especially paper/TLC), the retention factor is defined as
Since the spot cannot travel farther than the solvent front,
So cannot be more than 1.
- Check each statement
Option A: " value depends on the type of chromatography."
This is correct. Different chromatographic methods and stationary phases can change how far a substance moves, so depends on the chromatography setup.
Option B: "Higher value means higher adsorption."
This is incorrect. If a substance is more strongly adsorbed on the stationary phase, it moves less and hence has a lower value. Therefore, higher means lower adsorption (or greater affinity for the mobile phase).
Option C: " value is dependent on the mobile phase."
This is correct. Changing the solvent/mobile phase changes how far the compound travels, so changes.
Option D: "The value of cannot be more than one."
This is correct by definition since the solute cannot move beyond the solvent front.
- Conclusion
The incorrect statement is:
More from Basics of Organic Chemistry
- Which of these factors does not govern the stability of a conformation in acyclic compounds?2019 · MCQ
- If dichloromethane (DCM) and water () are used for differential extraction, which one of the following statements is correct ?2019 · MCQ
- What is the IUPAC name of the following compound ? Includes diagram2019 · MCQ
- The correct match between items I and II is : Includes table2019 · MCQ
- In the following compound, the favourable site/s for protonation is/are : Includes diagram2019 · MCQ
- The increasing order of the pKb of the following compound is : Includes diagram2019 · MCQ
- The IUPAC name for the following compound is : Includes diagram2019 · MCQ
- Among the following four aromatic compounds, which one will have the lowest melting point ?2019 · MCQ