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Basics of Organic Chemistry question

2019 · 10 Apr · Shift 2 · Q17
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Basics of Organic Chemistry question

2019 · 10 Apr · Shift 2 · Q17

JEE MainChemistryBasics of Organic ChemistryMCQ+4 / −1
In chromatography, which of the following statements is incorrect for Rf ?
  1. A
    Rf value depends on the type of chromatography.
  2. B
    Higher Rf value means higher adsorption.
  3. C
    Rf value is dependent on the mobile phase.
  4. D
    The value of Rf can not be more than one.
View written solutionFree

Correct answer: B

  1. Recall the definition of RfR_fRf​

In chromatography (especially paper/TLC), the retention factor is defined as

Rf=distance travelled by the solute (spot)distance travelled by the solvent frontR_f = \frac{\text{distance travelled by the solute (spot)}}{\text{distance travelled by the solvent front}}Rf​=distance travelled by the solvent frontdistance travelled by the solute (spot)​

Since the spot cannot travel farther than the solvent front,

0≤Rf≤10 \le R_f \le 10≤Rf​≤1

So RfR_fRf​ cannot be more than 1.


  1. Check each statement

Option A: "RfR_fRf​ value depends on the type of chromatography."

This is correct. Different chromatographic methods and stationary phases can change how far a substance moves, so RfR_fRf​ depends on the chromatography setup.

Option B: "Higher RfR_fRf​ value means higher adsorption."

This is incorrect. If a substance is more strongly adsorbed on the stationary phase, it moves less and hence has a lower RfR_fRf​ value. Therefore, higher RfR_fRf​ means lower adsorption (or greater affinity for the mobile phase).

Option C: "RfR_fRf​ value is dependent on the mobile phase."

This is correct. Changing the solvent/mobile phase changes how far the compound travels, so RfR_fRf​ changes.

Option D: "The value of RfR_fRf​ cannot be more than one."

This is correct by definition since the solute cannot move beyond the solvent front.


  1. Conclusion

The incorrect statement is:

B\boxed{\text{B}}B​

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