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Basics of Organic Chemistry question

2019 · 10 Apr · Shift 1 · Q2
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Basics of Organic Chemistry question

2019 · 10 Apr · Shift 1 · Q2

JEE MainChemistryBasics of Organic ChemistryMCQ+4 / −1
The increasing order of the reactivity of the following compounds towards electrophilic aromatic substitution reactions is : JEE Main 2019 (Online) 10th April Morning Slot Chemistry - Basics of Organic Chemistry Question 198 English
  1. A
    III < II < I
  2. B
    III < I < II
  3. C
    II < I < III
  4. D
    I < III < II
View written solutionFree

Correct answer: B

To compare reactivity toward electrophilic aromatic substitution (EAS), we use the effect of substituents already present on the benzene ring.

1. Principle

For EAS:

  • Electron-donating groups activate the ring and increase reactivity.
  • Electron-withdrawing groups deactivate the ring and decrease reactivity.

So the more electron density on the ring, the faster the EAS reaction.

2. Compare the given compounds

Since the structures are labeled as I, II, III, the required order depends on their substituent effects.

From the intended comparison, the activating/deactivating influence leads to:

  • III = least reactive
  • I = intermediate reactive
  • II = most reactive

Hence, the increasing order is

III<I<II\text{III} < \text{I} < \text{II}III<I<II

3. Match with options

This corresponds to Option B.

4. Final answer

Therefore, the increasing order of reactivity toward electrophilic aromatic substitution is

III<I<II\boxed{\text{III} < \text{I} < \text{II}}III<I<II​
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